BiPh3 - A convenient synthon for heavy alkaline-earth metal amides

Miriam M. Gillett-Kunnath, Jonathan G. MacLellan, Craig M. Forsyth, Philip C. Andrews, Glen B. Deacon, Karin Ruhlandt

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

Environmentally friendly, commercially available BiPh3 reacts with heavy alkaline-earth metals (Ae) and bulky trimethylsilylamines to give the corresponding amides [Ae{N(SiMe3)(R)}2(thf)n] (R = SiMe3, 2,4,6-Me3C6H2, 2,6- iPr2C6H3) in good yields, providing proof of concept for a general synthetic method.

Original languageEnglish (US)
Pages (from-to)4490-4492
Number of pages3
JournalChemical Communications
Issue number37
DOIs
StatePublished - 2008

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Alkaline Earth Metals
Alkaline earth metals
Amides
Heavy metals

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Gillett-Kunnath, M. M., MacLellan, J. G., Forsyth, C. M., Andrews, P. C., Deacon, G. B., & Ruhlandt, K. (2008). BiPh3 - A convenient synthon for heavy alkaline-earth metal amides. Chemical Communications, (37), 4490-4492. https://doi.org/10.1039/b806948d

BiPh3 - A convenient synthon for heavy alkaline-earth metal amides. / Gillett-Kunnath, Miriam M.; MacLellan, Jonathan G.; Forsyth, Craig M.; Andrews, Philip C.; Deacon, Glen B.; Ruhlandt, Karin.

In: Chemical Communications, No. 37, 2008, p. 4490-4492.

Research output: Contribution to journalArticle

Gillett-Kunnath, MM, MacLellan, JG, Forsyth, CM, Andrews, PC, Deacon, GB & Ruhlandt, K 2008, 'BiPh3 - A convenient synthon for heavy alkaline-earth metal amides', Chemical Communications, no. 37, pp. 4490-4492. https://doi.org/10.1039/b806948d
Gillett-Kunnath MM, MacLellan JG, Forsyth CM, Andrews PC, Deacon GB, Ruhlandt K. BiPh3 - A convenient synthon for heavy alkaline-earth metal amides. Chemical Communications. 2008;(37):4490-4492. https://doi.org/10.1039/b806948d
Gillett-Kunnath, Miriam M. ; MacLellan, Jonathan G. ; Forsyth, Craig M. ; Andrews, Philip C. ; Deacon, Glen B. ; Ruhlandt, Karin. / BiPh3 - A convenient synthon for heavy alkaline-earth metal amides. In: Chemical Communications. 2008 ; No. 37. pp. 4490-4492.
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