Barium triphenylmethanide: An examination of anion basicity

Jacob S. Alexander; Karin Ruhlandt-Senge

doi:10.1002/1521-3773(20010716)40:14<2658::AID-ANIE2658>3.0.CO;2-Y

Barium triphenylmethanide: An examination of anion basicity

Jacob S. Alexander, Karin Ruhlandt-Senge

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

51 Scopus citations

Abstract

Differences in anion basicity seem to be key for the formation of the first charge-separated barium triphenylmethanide (see structure) versus a novel heteroleptic vinyl ether which results from cleavage of the attendant [18]crown-6. Ba: green; O: red; P: yellow; N: blue.

Original language	English (US)
Pages (from-to)	2658-2660
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	40
Issue number	14
DOIs	https://doi.org/10.1002/1521-3773(20010716)40:14<2658::AID-ANIE2658>3.0.CO;2-Y
State	Published - Jul 16 2001

Keywords

Alkaline earth metals
Carbanions
Ion pairs
Triphenylmethane

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/1521-3773(20010716)40:14<2658::AID-ANIE2658>3.0.CO;2-Y

Cite this

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title = "Barium triphenylmethanide: An examination of anion basicity",

abstract = "Differences in anion basicity seem to be key for the formation of the first charge-separated barium triphenylmethanide (see structure) versus a novel heteroleptic vinyl ether which results from cleavage of the attendant [18]crown-6. Ba: green; O: red; P: yellow; N: blue.",

keywords = "Alkaline earth metals, Carbanions, Ion pairs, Triphenylmethane",

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T2 - An examination of anion basicity

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AU - Ruhlandt-Senge, Karin

PY - 2001/7/16

Y1 - 2001/7/16

N2 - Differences in anion basicity seem to be key for the formation of the first charge-separated barium triphenylmethanide (see structure) versus a novel heteroleptic vinyl ether which results from cleavage of the attendant [18]crown-6. Ba: green; O: red; P: yellow; N: blue.

AB - Differences in anion basicity seem to be key for the formation of the first charge-separated barium triphenylmethanide (see structure) versus a novel heteroleptic vinyl ether which results from cleavage of the attendant [18]crown-6. Ba: green; O: red; P: yellow; N: blue.

KW - Alkaline earth metals

KW - Carbanions

KW - Ion pairs

KW - Triphenylmethane

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ER -

Barium triphenylmethanide: An examination of anion basicity

Abstract

Keywords

ASJC Scopus subject areas

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