Abstract
Differences in anion basicity seem to be key for the formation of the first charge-separated barium triphenylmethanide (see structure) versus a novel heteroleptic vinyl ether which results from cleavage of the attendant [18]crown-6. Ba: green; O: red; P: yellow; N: blue.
Original language | English (US) |
---|---|
Pages (from-to) | 2658-2660 |
Number of pages | 3 |
Journal | Angewandte Chemie - International Edition |
Volume | 40 |
Issue number | 14 |
DOIs | |
State | Published - Jul 16 2001 |
Keywords
- Alkaline earth metals
- Carbanions
- Ion pairs
- Triphenylmethane
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)