Auxiliary-Directed Diastereoselectivity in the Claisen Rearrangement of Glycolate Esters

James Kallmerten, Thomas J. Gould

Research output: Contribution to journalArticle

36 Scopus citations

Abstract

Examples are presented in which the stereochemical course of the Claisen rearrangement of allylic glycolates is controlled by a chiral substituent appended to the glycolate hydroxyl (eq 1).

Original languageEnglish (US)
Pages (from-to)1152-1155
Number of pages4
JournalJournal of Organic Chemistry
Volume51
Issue number7
DOIs
StatePublished - Apr 1 1986

ASJC Scopus subject areas

  • Organic Chemistry

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