Auxiliary-Directed Diastereoselectivity in the Claisen Rearrangement of Glycolate Esters

James Kallmerten; Thomas J. Gould

doi:10.1021/jo00357a048

Auxiliary-Directed Diastereoselectivity in the Claisen Rearrangement of Glycolate Esters

James Kallmerten, Thomas J. Gould

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

Examples are presented in which the stereochemical course of the Claisen rearrangement of allylic glycolates is controlled by a chiral substituent appended to the glycolate hydroxyl (eq 1).

Original language	English (US)
Pages (from-to)	1152-1155
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	51
Issue number	7
DOIs	https://doi.org/10.1021/jo00357a048
State	Published - Apr 1 1986

ASJC Scopus subject areas

Organic Chemistry

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title = "Auxiliary-Directed Diastereoselectivity in the Claisen Rearrangement of Glycolate Esters",

abstract = "Examples are presented in which the stereochemical course of the Claisen rearrangement of allylic glycolates is controlled by a chiral substituent appended to the glycolate hydroxyl (eq 1).",

author = "James Kallmerten and Gould, {Thomas J.}",

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N2 - Examples are presented in which the stereochemical course of the Claisen rearrangement of allylic glycolates is controlled by a chiral substituent appended to the glycolate hydroxyl (eq 1).

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Auxiliary-Directed Diastereoselectivity in the Claisen Rearrangement of Glycolate Esters

Abstract

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