Anion influences on the construction of one-dimensional structures of the Cu(II)-bisterpy family (bisterpy=2,2′:4′,4″:2″,2‴-quarterpyridyl, 6′,6″-di-2-pyridiine)

Bon Kweon Koo; Lindsey Bewley; Vladimir Golub; Randy S. Rarig; Eric Burkholder; Charles J. O'Connor; Jon Zubieta

doi:10.1016/S0020-1693(03)00186-5

Anion influences on the construction of one-dimensional structures of the Cu(II)-bisterpy family (bisterpy=2,2′:4′,4″:2″,2‴-quarterpyridyl, 6′,6″-di-2-pyridiine)

Bon Kweon Koo, Lindsey Bewley, Vladimir Golub, Randy S. Rarig, Eric Burkholder, Charles J. O'Connor, Jon Zubieta

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

The hydrothermal reactions of M(II) salts with 2,2′:4′,4″:2″,2‴-quaterpyridyl, 6′,6″-di-2-pyridine (bisterpy) in the presence of a variety of anionic subunits have been investigated. The compounds [Cu₂(bisterpy)(H₂O)₂Cl₂]Cl ₂ (1), [Cu₂(bisterpy)Br₄] (2), and [Cu₂(bisterpy) (NO₃)₄]·2H₂O (3·2H₂O) are molecular. In contrast, [Cu₂(bisterpy)Cl₂(PF₆)] (4), [Mn₂(bisterpy)(SO₄)₂] (5), [Zn₂(bisterpy)(SO₄)₂] (6), [Cu₂(phbisterpy)(SO₄)₂]·2H ₂O (7·2H₂O), [Cu₂(bisterpy)(MoO₄)₂] (8), [Zn₂(bisterpy)(MoO₄)₂] (9), [Cu₂(bisterpy)(H₂O)₂(SO₄)] [Mo₄O₁₃]·1.25H₂O (10·1.25H₂O) and [Cu₂(bisterpy)Mo₈O₂₆]·2H₂O (11·2H₂O) are one-dimensional materials. The structural evolution of the molybdate series 8, 10, and 11 illustrates the profound influence of hydrothermal reaction conditions on product identity and architecture. The (PF₆)^- bridged solid 4 is mixed valence Cu(I)/Cu(II), a feature consistent with the magnetic properties of this material.

Original language	English (US)
Pages (from-to)	167-176
Number of pages	10
Journal	Inorganica Chimica Acta
Volume	351
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(03)00186-5
State	Published - Jul 22 2003
Externally published	Yes

Keywords

Cu(II)-bisterpy family
Hydrothermal reactions
One-dimensional materials

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0020-1693(03)00186-5

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Anion influences on the construction of one-dimensional structures of the Cu(II)-bisterpy family (bisterpy=2,2′:4′,4″:2″,2‴-quarterpyridyl, 6′,6″-di-2-pyridiine). / Koo, Bon Kweon; Bewley, Lindsey; Golub, Vladimir et al.
In: Inorganica Chimica Acta, Vol. 351, No. 1, 22.07.2003, p. 167-176.

Research output: Contribution to journal › Article › peer-review

@article{076b1631cd8c4054a9f44c5edae09786,

title = "Anion influences on the construction of one-dimensional structures of the Cu(II)-bisterpy family (bisterpy=2,2′:4′,4″:2″,2‴-quarterpyridyl, 6′,6″-di-2-pyridiine)",

abstract = "The hydrothermal reactions of M(II) salts with 2,2′:4′,4″:2″,2‴-quaterpyridyl, 6′,6″-di-2-pyridine (bisterpy) in the presence of a variety of anionic subunits have been investigated. The compounds [Cu2(bisterpy)(H2O)2Cl2]Cl 2 (1), [Cu2(bisterpy)Br4] (2), and [Cu2(bisterpy) (NO3)4]·2H2O (3·2H2O) are molecular. In contrast, [Cu2(bisterpy)Cl2(PF6)] (4), [Mn2(bisterpy)(SO4)2] (5), [Zn2(bisterpy)(SO4)2] (6), [Cu2(phbisterpy)(SO4)2]·2H 2O (7·2H2O), [Cu2(bisterpy)(MoO4)2] (8), [Zn2(bisterpy)(MoO4)2] (9), [Cu2(bisterpy)(H2O)2(SO4)] [Mo4O13]·1.25H2O (10·1.25H2O) and [Cu2(bisterpy)Mo8O26]·2H2O (11·2H2O) are one-dimensional materials. The structural evolution of the molybdate series 8, 10, and 11 illustrates the profound influence of hydrothermal reaction conditions on product identity and architecture. The (PF6)- bridged solid 4 is mixed valence Cu(I)/Cu(II), a feature consistent with the magnetic properties of this material.",

keywords = "Cu(II)-bisterpy family, Hydrothermal reactions, One-dimensional materials",

author = "Koo, {Bon Kweon} and Lindsey Bewley and Vladimir Golub and Rarig, {Randy S.} and Eric Burkholder and O'Connor, {Charles J.} and Jon Zubieta",

note = "Funding Information: This work was supported by NSF grant CHE9987471. L.B. acknowledges summer support from the NSF REU Program, CHE9987838.",

year = "2003",

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doi = "10.1016/S0020-1693(03)00186-5",

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T1 - Anion influences on the construction of one-dimensional structures of the Cu(II)-bisterpy family (bisterpy=2,2′:4′,4″:2″,2‴-quarterpyridyl, 6′,6″-di-2-pyridiine)

AU - Koo, Bon Kweon

AU - Bewley, Lindsey

AU - Golub, Vladimir

AU - Rarig, Randy S.

AU - Burkholder, Eric

AU - O'Connor, Charles J.

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by NSF grant CHE9987471. L.B. acknowledges summer support from the NSF REU Program, CHE9987838.

PY - 2003/7/22

Y1 - 2003/7/22

N2 - The hydrothermal reactions of M(II) salts with 2,2′:4′,4″:2″,2‴-quaterpyridyl, 6′,6″-di-2-pyridine (bisterpy) in the presence of a variety of anionic subunits have been investigated. The compounds [Cu2(bisterpy)(H2O)2Cl2]Cl 2 (1), [Cu2(bisterpy)Br4] (2), and [Cu2(bisterpy) (NO3)4]·2H2O (3·2H2O) are molecular. In contrast, [Cu2(bisterpy)Cl2(PF6)] (4), [Mn2(bisterpy)(SO4)2] (5), [Zn2(bisterpy)(SO4)2] (6), [Cu2(phbisterpy)(SO4)2]·2H 2O (7·2H2O), [Cu2(bisterpy)(MoO4)2] (8), [Zn2(bisterpy)(MoO4)2] (9), [Cu2(bisterpy)(H2O)2(SO4)] [Mo4O13]·1.25H2O (10·1.25H2O) and [Cu2(bisterpy)Mo8O26]·2H2O (11·2H2O) are one-dimensional materials. The structural evolution of the molybdate series 8, 10, and 11 illustrates the profound influence of hydrothermal reaction conditions on product identity and architecture. The (PF6)- bridged solid 4 is mixed valence Cu(I)/Cu(II), a feature consistent with the magnetic properties of this material.

AB - The hydrothermal reactions of M(II) salts with 2,2′:4′,4″:2″,2‴-quaterpyridyl, 6′,6″-di-2-pyridine (bisterpy) in the presence of a variety of anionic subunits have been investigated. The compounds [Cu2(bisterpy)(H2O)2Cl2]Cl 2 (1), [Cu2(bisterpy)Br4] (2), and [Cu2(bisterpy) (NO3)4]·2H2O (3·2H2O) are molecular. In contrast, [Cu2(bisterpy)Cl2(PF6)] (4), [Mn2(bisterpy)(SO4)2] (5), [Zn2(bisterpy)(SO4)2] (6), [Cu2(phbisterpy)(SO4)2]·2H 2O (7·2H2O), [Cu2(bisterpy)(MoO4)2] (8), [Zn2(bisterpy)(MoO4)2] (9), [Cu2(bisterpy)(H2O)2(SO4)] [Mo4O13]·1.25H2O (10·1.25H2O) and [Cu2(bisterpy)Mo8O26]·2H2O (11·2H2O) are one-dimensional materials. The structural evolution of the molybdate series 8, 10, and 11 illustrates the profound influence of hydrothermal reaction conditions on product identity and architecture. The (PF6)- bridged solid 4 is mixed valence Cu(I)/Cu(II), a feature consistent with the magnetic properties of this material.

KW - Cu(II)-bisterpy family

KW - Hydrothermal reactions

KW - One-dimensional materials

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ER -

Anion influences on the construction of one-dimensional structures of the Cu(II)-bisterpy family (bisterpy=2,2′:4′,4″:2″,2‴-quarterpyridyl, 6′,6″-di-2-pyridiine)

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