Analysis of gel formation in imidazole‐catalyzed epoxies

M. S. Heise, G. C. Martin, J. T. Gotro

Research output: Contribution to journalArticlepeer-review

7 Scopus citations


The network formation processes for imidazole‐cured epoxy resins were examined by relating the reaction chemistry and the physical properties during cure. Network formation models were developed based on kinetic studies and the laws of conditional probability. These models were used to predict the weight‐average molecular weight, the gel point, and the sol fraction as a function of the resin composition and the processing conditions. Rheological and extraction experiments were conducted to confirm the model results and to develop criteria for identifying the gel point.

Original languageEnglish (US)
Pages (from-to)529-534
Number of pages6
JournalPolymer Engineering & Science
Issue number8
StatePublished - Apr 1992

ASJC Scopus subject areas

  • General Chemistry
  • Polymers and Plastics
  • Materials Chemistry


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