TY - JOUR
T1 - An octanuclear alkoxy-polyoxomolybdate. The crystal and molecular structure of [(n-C4H9)4N]2[Mo 8O20(OMe)4{MeC(CH2O) 3}2]
AU - Ma, Lidun
AU - Liu, Shuncheng
AU - Zubieta, Jon
PY - 1989
Y1 - 1989
N2 - Reaction of [(n-C4H9)4N] 2[Mo2O7] with 2-hydroxymethyl-2-methylpropane- 1,3-diol yields [(C4H9)4N]2[Mo 8O20(OMe)4{MeC(MeO)3}2] (1), an alkoxypolyoxomolybdate consisting of two tetranuclear [Mo 4O10(OMe)2{MeC(CH2O) 3]- moieties, composed of edge-sharing MoO6 octahedra, which are connected via two corner-sharing interactions through bridging oxo-groups; thermal degradation of (1) yields dimethyl ether, formaldehyde, methanol, and water as gaseous products.
AB - Reaction of [(n-C4H9)4N] 2[Mo2O7] with 2-hydroxymethyl-2-methylpropane- 1,3-diol yields [(C4H9)4N]2[Mo 8O20(OMe)4{MeC(MeO)3}2] (1), an alkoxypolyoxomolybdate consisting of two tetranuclear [Mo 4O10(OMe)2{MeC(CH2O) 3]- moieties, composed of edge-sharing MoO6 octahedra, which are connected via two corner-sharing interactions through bridging oxo-groups; thermal degradation of (1) yields dimethyl ether, formaldehyde, methanol, and water as gaseous products.
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U2 - 10.1039/C39890000440
DO - 10.1039/C39890000440
M3 - Article
AN - SCOPUS:37049086443
SN - 0022-4936
SP - 440
EP - 442
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 7
ER -