An effective strategy for acyclic synthesis via iterative rearrangement of allylic glycolates. Synthesis of a pine sawfly pheromone

James Kallmerten, Michael Balestra

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22 Scopus citations

Abstract

The stereocontrolled preparation of extended acyclic systems using the iterative enolate Claisen rearrangement of allylic glycolates is described. This strategy has been demonstrated in the stereospecific synthesis of a pine sawfly pheromone.

Original languageEnglish (US)
Pages (from-to)2855-2857
Number of pages3
JournalJournal of Organic Chemistry
Volume51
Issue number14
StatePublished - 1986

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ASJC Scopus subject areas

  • Organic Chemistry

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