An asymmetric triply-bridged MoV complex with bridging azido-ligand. The structures of [Mo2O2(μ-N3){S(CH 2)3S}3]- and its precursor [MoO{S(CH2)3S}2]-

Peter T. Bishop; Jonathan R. Dilworth; John Hutchinson; Jon A. Zubieta

doi:10.1039/C39820001052

An asymmetric triply-bridged MoV complex with bridging azido-ligand. The structures of [Mo₂O₂(μ-N₃){S(CH ₂)₃S}₃]^- and its precursor [MoO{S(CH₂)₃S}₂]^-

Peter T. Bishop, Jonathan R. Dilworth, John Hutchinson, Jon A. Zubieta

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

The complex [MoO(SCH₂CH₂CH₂S) ₂]^- reacts with HN₃ in methanol to give [Mo₂O₂(μ-N₃)(SCH₂CH ₂CH₂S)₃]^-; X-ray crystallography shows the former anion to have tetragonal pyramidal co-ordination about Mo with an apical oxo-group and the latter to be an asymmetric dinuclear complex with a triple bridge comprising two dithiolate sulphurs and a bent azide group linking two distinct pseudo-octahedral molybdenums.

Original language	English (US)
Pages (from-to)	1052-1053
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/C39820001052
State	Published - 1982
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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An asymmetric triply-bridged MoV complex with bridging azido-ligand. The structures of [Mo₂O₂(μ-N₃){S(CH ₂)₃S}₃]^- and its precursor [MoO{S(CH₂)₃S}₂]^-. / Bishop, Peter T.; Dilworth, Jonathan R.; Hutchinson, John et al.
In: Journal of the Chemical Society, Chemical Communications, No. 18, 1982, p. 1052-1053.

Research output: Contribution to journal › Article › peer-review

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title = "An asymmetric triply-bridged MoV complex with bridging azido-ligand. The structures of [Mo2O2(μ-N3){S(CH 2)3S}3]- and its precursor [MoO{S(CH2)3S}2]-",

abstract = "The complex [MoO(SCH2CH2CH2S) 2]- reacts with HN3 in methanol to give [Mo2O2(μ-N3)(SCH2CH 2CH2S)3]-; X-ray crystallography shows the former anion to have tetragonal pyramidal co-ordination about Mo with an apical oxo-group and the latter to be an asymmetric dinuclear complex with a triple bridge comprising two dithiolate sulphurs and a bent azide group linking two distinct pseudo-octahedral molybdenums.",

author = "Bishop, {Peter T.} and Dilworth, {Jonathan R.} and John Hutchinson and Zubieta, {Jon A.}",

year = "1982",

doi = "10.1039/C39820001052",

language = "English (US)",

pages = "1052--1053",

journal = "Journal of the Chemical Society, Chemical Communications",

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T1 - An asymmetric triply-bridged MoV complex with bridging azido-ligand. The structures of [Mo2O2(μ-N3){S(CH 2)3S}3]- and its precursor [MoO{S(CH2)3S}2]-

AU - Bishop, Peter T.

AU - Dilworth, Jonathan R.

AU - Hutchinson, John

AU - Zubieta, Jon A.

PY - 1982

Y1 - 1982

N2 - The complex [MoO(SCH2CH2CH2S) 2]- reacts with HN3 in methanol to give [Mo2O2(μ-N3)(SCH2CH 2CH2S)3]-; X-ray crystallography shows the former anion to have tetragonal pyramidal co-ordination about Mo with an apical oxo-group and the latter to be an asymmetric dinuclear complex with a triple bridge comprising two dithiolate sulphurs and a bent azide group linking two distinct pseudo-octahedral molybdenums.

AB - The complex [MoO(SCH2CH2CH2S) 2]- reacts with HN3 in methanol to give [Mo2O2(μ-N3)(SCH2CH 2CH2S)3]-; X-ray crystallography shows the former anion to have tetragonal pyramidal co-ordination about Mo with an apical oxo-group and the latter to be an asymmetric dinuclear complex with a triple bridge comprising two dithiolate sulphurs and a bent azide group linking two distinct pseudo-octahedral molybdenums.

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An asymmetric triply-bridged MoV complex with bridging azido-ligand. The structures of [Mo₂O₂(μ-N₃){S(CH ₂)₃S}₃]^- and its precursor [MoO{S(CH₂)₃S}₂]^-

Abstract

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