An asymmetric dinuclear complex of rhodium(II) with bridging thiolato-ligands chelated via sulphur and an alkene substituent. The x-ray crystal structure of [Rh2{μ2-SC6H 2Pri2-4,6;2-(η2-MeC=CH 2)}2{SC6H2-2,4,6-Pri 3}2(NCMe)]

Peter T. Bishop; Jonathan R. Dilworth; Terence Nicholson; Jon A. Zubieta

doi:10.1039/C39860001123

An asymmetric dinuclear complex of rhodium(II) with bridging thiolato-ligands chelated via sulphur and an alkene substituent. The x-ray crystal structure of [Rh₂{μ₂-SC₆H ₂Prⁱ₂-4,6;2-(η²-MeC=CH ₂)}₂{SC₆H₂-2,4,6-Prⁱ ₃}₂(NCMe)]

Peter T. Bishop, Jonathan R. Dilworth, Terence Nicholson, Jon A. Zubieta

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The title complex (1) was synthesised by reaction of RhCl₃ with 2,4,6-tri-isopropylbenzenethiol in MeCN, and it has an asymmetric dinuclear structure with two bridging thiolate ligands with η²,Rh-bound unsaturated groups formed by dehydrogenation of isopropyl substituents; the Rh-Rh bond distance is 2.756(1) Å with the RhS₂Rh system bent about the S-S vector to give a butterfly configuration.

Original language	English (US)
Pages (from-to)	1123-1125
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	14
DOIs	https://doi.org/10.1039/C39860001123
State	Published - 1986
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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Bishop, P. T., Dilworth, J. R., Nicholson, T., & Zubieta, J. A. (1986). An asymmetric dinuclear complex of rhodium(II) with bridging thiolato-ligands chelated via sulphur and an alkene substituent. The x-ray crystal structure of [Rh₂{μ₂-SC₆H ₂Prⁱ₂-4,6;2-(η²-MeC=CH ₂)}₂{SC₆H₂-2,4,6-Prⁱ ₃}₂(NCMe)]. Journal of the Chemical Society, Chemical Communications, (14), 1123-1125. https://doi.org/10.1039/C39860001123

An asymmetric dinuclear complex of rhodium(II) with bridging thiolato-ligands chelated via sulphur and an alkene substituent. The x-ray crystal structure of [Rh₂{μ₂-SC₆H ₂Prⁱ₂-4,6;2-(η²-MeC=CH ₂)}₂{SC₆H₂-2,4,6-Prⁱ ₃}₂(NCMe)]. / Bishop, Peter T.; Dilworth, Jonathan R.; Nicholson, Terence et al.
In: Journal of the Chemical Society, Chemical Communications, No. 14, 1986, p. 1123-1125.

Research output: Contribution to journal › Article › peer-review

Bishop, PT, Dilworth, JR, Nicholson, T & Zubieta, JA 1986, 'An asymmetric dinuclear complex of rhodium(II) with bridging thiolato-ligands chelated via sulphur and an alkene substituent. The x-ray crystal structure of [Rh₂{μ₂-SC₆H ₂Prⁱ₂-4,6;2-(η²-MeC=CH ₂)}₂{SC₆H₂-2,4,6-Prⁱ ₃}₂(NCMe)]', Journal of the Chemical Society, Chemical Communications, no. 14, pp. 1123-1125. https://doi.org/10.1039/C39860001123

Bishop PT, Dilworth JR, Nicholson T, Zubieta JA. An asymmetric dinuclear complex of rhodium(II) with bridging thiolato-ligands chelated via sulphur and an alkene substituent. The x-ray crystal structure of [Rh₂{μ₂-SC₆H ₂Prⁱ₂-4,6;2-(η²-MeC=CH ₂)}₂{SC₆H₂-2,4,6-Prⁱ ₃}₂(NCMe)]. Journal of the Chemical Society, Chemical Communications. 1986;(14):1123-1125. doi: 10.1039/C39860001123

Bishop, Peter T. ; Dilworth, Jonathan R. ; Nicholson, Terence et al. / An asymmetric dinuclear complex of rhodium(II) with bridging thiolato-ligands chelated via sulphur and an alkene substituent. The x-ray crystal structure of [Rh₂{μ₂-SC₆H ₂Prⁱ₂-4,6;2-(η²-MeC=CH ₂)}₂{SC₆H₂-2,4,6-Prⁱ ₃}₂(NCMe)]. In: Journal of the Chemical Society, Chemical Communications. 1986 ; No. 14. pp. 1123-1125.

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