Alkali metal diphenylmethanides: Synthetic, computational and structural studies

Jacob S. Alexander, Damian G. Allis, Weijie Teng, Karin Ruhlandt-Senge

Research output: Contribution to journalArticle

7 Scopus citations

Abstract

In search of new synthetic precursors for the preparation of alkaline earth organometallic compounds, we investigated the application of a powerful desilylation reaction to cleanly afford a variety of contact and charge-separated alkali metal derivatives without the difficulties commonly encountered in other methods. The resulting diphenylmethanides display both contact molecules and separated ion pairs. Analysis of the structural data demonstrates that simple electrostatic models are insufficient for predieting and explaining the solid-state structures of these complexes. Detailed computational investigations were performed to probe the nature of the metal-anion and metal-donor interactions and determine the contributions of each to the observed solid-state structures.

Original languageEnglish (US)
Pages (from-to)9899-9911
Number of pages13
JournalChemistry - A European Journal
Volume13
Issue number35
DOIs
StatePublished - Dec 26 2007

Keywords

  • Alkali metals
  • Density functional calculations
  • Diphenyl-methanides
  • Ion association
  • Structure elucidation

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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