Activation of O2 by a binuclear copper(I) compound. Hydroxylation of a new xylyl-binucleating ligand to produce a phenoxy-bridged binuclear copper(II) complex; x-ray crystal structure of [Cu2{OC 6H3[CH2N(CH2CH2py) 2]2-2,6}(OMe)] (py = 2-pyridyl)

Kenneth D. Karlin; Phillip L. Dahlstrom; Stephen N. Cozzette; Patricia M. Scensny; Jon Zubieta

doi:10.1039/C39810000881

Activation of O₂ by a binuclear copper(I) compound. Hydroxylation of a new xylyl-binucleating ligand to produce a phenoxy-bridged binuclear copper(II) complex; x-ray crystal structure of [Cu₂{OC ₆H₃[CH₂N(CH₂CH₂py) ₂]₂-2,6}(OMe)] (py = 2-pyridyl)

Kenneth D. Karlin, Phillip L. Dahlstrom, Stephen N. Cozzette, Patricia M. Scensny, Jon Zubieta

Research output: Contribution to journal › Article › peer-review

114 Scopus citations

Abstract

Reaction of O₂ with a binuclear Cu^I species derived from a new meta-xylyl-binucleating ligand, NNN′N′-tetrakis[2-(2- pyridyl)ethyl]-α,α′-diamino-m-xylene [m-xyl(py)], has resulted in hydroxylation of the ligand to produce the binuclear Cu^II complex (1); the X-ray crystal structure of the dication of (1) shows two pentaco-ordinate Cu^II ions bridged by the phenoxy-group of the ligand and a methoxy-group.

Original language	English (US)
Pages (from-to)	881-882
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/C39810000881
State	Published - 1981
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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Karlin, K. D., Dahlstrom, P. L., Cozzette, S. N., Scensny, P. M., & Zubieta, J. (1981). Activation of O₂ by a binuclear copper(I) compound. Hydroxylation of a new xylyl-binucleating ligand to produce a phenoxy-bridged binuclear copper(II) complex; x-ray crystal structure of [Cu₂{OC ₆H₃[CH₂N(CH₂CH₂py) ₂]₂-2,6}(OMe)] (py = 2-pyridyl). Journal of the Chemical Society, Chemical Communications, (17), 881-882. https://doi.org/10.1039/C39810000881

Activation of O₂ by a binuclear copper(I) compound. Hydroxylation of a new xylyl-binucleating ligand to produce a phenoxy-bridged binuclear copper(II) complex; x-ray crystal structure of [Cu₂{OC ₆H₃[CH₂N(CH₂CH₂py) ₂]₂-2,6}(OMe)] (py = 2-pyridyl). / Karlin, Kenneth D.; Dahlstrom, Phillip L.; Cozzette, Stephen N. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 17, 1981, p. 881-882.

Research output: Contribution to journal › Article › peer-review

Karlin, KD, Dahlstrom, PL, Cozzette, SN, Scensny, PM & Zubieta, J 1981, 'Activation of O₂ by a binuclear copper(I) compound. Hydroxylation of a new xylyl-binucleating ligand to produce a phenoxy-bridged binuclear copper(II) complex; x-ray crystal structure of [Cu₂{OC ₆H₃[CH₂N(CH₂CH₂py) ₂]₂-2,6}(OMe)] (py = 2-pyridyl)', Journal of the Chemical Society, Chemical Communications, no. 17, pp. 881-882. https://doi.org/10.1039/C39810000881

Karlin KD, Dahlstrom PL, Cozzette SN, Scensny PM, Zubieta J. Activation of O₂ by a binuclear copper(I) compound. Hydroxylation of a new xylyl-binucleating ligand to produce a phenoxy-bridged binuclear copper(II) complex; x-ray crystal structure of [Cu₂{OC ₆H₃[CH₂N(CH₂CH₂py) ₂]₂-2,6}(OMe)] (py = 2-pyridyl). Journal of the Chemical Society, Chemical Communications. 1981;(17):881-882. doi: 10.1039/C39810000881

Karlin, Kenneth D. ; Dahlstrom, Phillip L. ; Cozzette, Stephen N. et al. / Activation of O₂ by a binuclear copper(I) compound. Hydroxylation of a new xylyl-binucleating ligand to produce a phenoxy-bridged binuclear copper(II) complex; x-ray crystal structure of [Cu₂{OC ₆H₃[CH₂N(CH₂CH₂py) ₂]₂-2,6}(OMe)] (py = 2-pyridyl). In: Journal of the Chemical Society, Chemical Communications. 1981 ; No. 17. pp. 881-882.

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