A two-dimensional network constructed from hexamolybdate, octamolybdate and [Cu3(4,7-phen)3]3+ clusters: [{Cu3(4,7-phen)3}2{Mo14O 45}]

Douglas Hagrman, Pamela J. Zapf, Jon Zubieta

Research output: Contribution to journalArticle

187 Scopus citations

Abstract

The hydrothermal reaction of Cu(SO4)·H2O, MoO3,4,7-phenanthroline and water yields [{Cu3(4,7-phen)3}2(Mo14O 45)], a material exhibiting a two-dimensional network constructed from (Mo6O19)2- and (Mo8O26)4- clusters linked through planar cyclic [Cu3(4,7-phen)33]+ clusters.

Original languageEnglish (US)
Pages (from-to)1283-1284
Number of pages2
JournalChemical Communications
Issue number12
DOIs
StatePublished - Jun 21 1998

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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