A two-dimensional network constructed from hexamolybdate, octamolybdate and [Cu3(4,7-phen)3]3+ clusters: [{Cu3(4,7-phen)3}2{Mo14O 45}]

Douglas Hagrman; Pamela J. Zapf; Jon Zubieta

doi:10.1039/a801742e

A two-dimensional network constructed from hexamolybdate, octamolybdate and [Cu₃(4,7-phen)₃]³⁺ clusters: [{Cu₃(4,7-phen)₃}₂{Mo₁₄O ₄₅}]

Douglas Hagrman, Pamela J. Zapf, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

195 Scopus citations

Abstract

The hydrothermal reaction of Cu(SO₄)·H₂O, MoO₃,4,7-phenanthroline and water yields [{Cu₃(4,7-phen)₃}₂(Mo₁₄O ₄₅)], a material exhibiting a two-dimensional network constructed from (Mo₆O₁₉)^2- and (Mo₈O₂₆)^4- clusters linked through planar cyclic [Cu₃(4,7-phen)₃³]⁺ clusters.

Original language	English (US)
Pages (from-to)	1283-1284
Number of pages	2
Journal	Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/a801742e
State	Published - Jun 21 1998

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "The hydrothermal reaction of Cu(SO4)·H2O, MoO3,4,7-phenanthroline and water yields [{Cu3(4,7-phen)3}2(Mo14O 45)], a material exhibiting a two-dimensional network constructed from (Mo6O19)2- and (Mo8O26)4- clusters linked through planar cyclic [Cu3(4,7-phen)33]+ clusters.",

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AU - Hagrman, Douglas

AU - Zapf, Pamela J.

AU - Zubieta, Jon

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AB - The hydrothermal reaction of Cu(SO4)·H2O, MoO3,4,7-phenanthroline and water yields [{Cu3(4,7-phen)3}2(Mo14O 45)], a material exhibiting a two-dimensional network constructed from (Mo6O19)2- and (Mo8O26)4- clusters linked through planar cyclic [Cu3(4,7-phen)33]+ clusters.

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A two-dimensional network constructed from hexamolybdate, octamolybdate and [Cu₃(4,7-phen)₃]³⁺ clusters: [{Cu₃(4,7-phen)₃}₂{Mo₁₄O ₄₅}]

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