TY - JOUR
T1 - A two-dimensional copper(II) molybdate, [{Cu2(tpyprz)}Mo 8O26] (tpyprz is 2,3,5,6-tetra-2-pyridyl-1,4-dihydro- pyrazine)
AU - Zubieta, Jon
AU - Armatas, N. Gabriel
PY - 2007/6/6
Y1 - 2007/6/6
N2 - In the title compound, poly[2-2,3,5,6-tetra-2-pyridyl-1,4-dihydro-pyrazine - hexa-cosa-oxidoocta-molybdato-dicopper(II)], [Cu2Mo8O26(C24H16N6)], the organic linker 2,3,5,6-tetra-2-pyridyl-1,4-dihydro-pyrazine (tpyprz) brings together four [Mo8O26]4- clusters through the cationic bridge [Cu2(tpyprz)]4+ to from a two-dimensional layer. The copper(II) cation is five-coordinate in a distorted square-pyramidal configuration, bonding to three N atoms from the tpyprz ligand and two terminal O atoms from the molybdenum cluster. The [Mo8O26]4- cluster shows bonding only through the terminal O atoms attached to the octa-hedrally coordinated Mo atom along the central axis of the cluster.
AB - In the title compound, poly[2-2,3,5,6-tetra-2-pyridyl-1,4-dihydro-pyrazine - hexa-cosa-oxidoocta-molybdato-dicopper(II)], [Cu2Mo8O26(C24H16N6)], the organic linker 2,3,5,6-tetra-2-pyridyl-1,4-dihydro-pyrazine (tpyprz) brings together four [Mo8O26]4- clusters through the cationic bridge [Cu2(tpyprz)]4+ to from a two-dimensional layer. The copper(II) cation is five-coordinate in a distorted square-pyramidal configuration, bonding to three N atoms from the tpyprz ligand and two terminal O atoms from the molybdenum cluster. The [Mo8O26]4- cluster shows bonding only through the terminal O atoms attached to the octa-hedrally coordinated Mo atom along the central axis of the cluster.
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U2 - 10.1107/S1600536807027390
DO - 10.1107/S1600536807027390
M3 - Article
AN - SCOPUS:34547183631
SN - 1600-5368
VL - 63
SP - m1924
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 7
ER -