A triply-bridged binuclear hydrazidomolybdenum(v) complex with terminal, bridging, and 'dangling' thiolate ligands. The chemical and structural characterization of [HNEt3]2[Mo2(NNPh)(NNHPh) (SCH2CH2S)3(SCH2CH 2SH)]·2/3H2NNHPh

Tze Chen Hsieh, Kassu Gebreyes, J. Zubieta

Research output: Contribution to journalArticle

15 Scopus citations

Abstract

The title compound has been obtained by treating [Mo(NNHPh) 2(butane-2,3-diolate)2]·H2NNHPh with excess of dimercaptoethane in methanol; X-ray crystallography reveals the first example of a binuclear bis-hydrazido complex and a unique instance of a molybdenum(V) complex exhibiting thiolate co-ordination trans to a strongly π-bonding group.

Original languageEnglish (US)
Pages (from-to)1172-1174
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number17
DOIs
StatePublished - Jan 1 1984
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

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