A triply-bridged binuclear hydrazidomolybdenum(v) complex with terminal, bridging, and 'dangling' thiolate ligands. The chemical and structural characterization of [HNEt3]2[Mo2(NNPh)(NNHPh) (SCH2CH2S)3(SCH2CH 2SH)]·2/3H2NNHPh

Tze Chen Hsieh; Kassu Gebreyes; J. Zubieta

doi:10.1039/C39840001172

A triply-bridged binuclear hydrazidomolybdenum(v) complex with terminal, bridging, and 'dangling' thiolate ligands. The chemical and structural characterization of [HNEt₃]₂[Mo₂(NNPh)(NNHPh) (SCH₂CH₂S)₃(SCH₂CH ₂SH)]·2/3H₂NNHPh

Tze Chen Hsieh, Kassu Gebreyes, J. Zubieta

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The title compound has been obtained by treating [Mo(NNHPh) ₂(butane-2,3-diolate)₂]·H₂NNHPh with excess of dimercaptoethane in methanol; X-ray crystallography reveals the first example of a binuclear bis-hydrazido complex and a unique instance of a molybdenum(V) complex exhibiting thiolate co-ordination trans to a strongly π-bonding group.

Original language	English (US)
Pages (from-to)	1172-1174
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/C39840001172
State	Published - 1984
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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Hsieh, T. C., Gebreyes, K., & Zubieta, J. (1984). A triply-bridged binuclear hydrazidomolybdenum(v) complex with terminal, bridging, and 'dangling' thiolate ligands. The chemical and structural characterization of [HNEt₃]₂[Mo₂(NNPh)(NNHPh) (SCH₂CH₂S)₃(SCH₂CH ₂SH)]·2/3H₂NNHPh. Journal of the Chemical Society, Chemical Communications, (17), 1172-1174. https://doi.org/10.1039/C39840001172

A triply-bridged binuclear hydrazidomolybdenum(v) complex with terminal, bridging, and 'dangling' thiolate ligands. The chemical and structural characterization of [HNEt₃]₂[Mo₂(NNPh)(NNHPh) (SCH₂CH₂S)₃(SCH₂CH ₂SH)]·2/3H₂NNHPh. / Hsieh, Tze Chen; Gebreyes, Kassu; Zubieta, J.
In: Journal of the Chemical Society, Chemical Communications, No. 17, 1984, p. 1172-1174.

Research output: Contribution to journal › Article › peer-review

Hsieh, TC, Gebreyes, K & Zubieta, J 1984, 'A triply-bridged binuclear hydrazidomolybdenum(v) complex with terminal, bridging, and 'dangling' thiolate ligands. The chemical and structural characterization of [HNEt₃]₂[Mo₂(NNPh)(NNHPh) (SCH₂CH₂S)₃(SCH₂CH ₂SH)]·2/3H₂NNHPh', Journal of the Chemical Society, Chemical Communications, no. 17, pp. 1172-1174. https://doi.org/10.1039/C39840001172

Hsieh, Tze Chen ; Gebreyes, Kassu ; Zubieta, J. / A triply-bridged binuclear hydrazidomolybdenum(v) complex with terminal, bridging, and 'dangling' thiolate ligands. The chemical and structural characterization of [HNEt₃]₂[Mo₂(NNPh)(NNHPh) (SCH₂CH₂S)₃(SCH₂CH ₂SH)]·2/3H₂NNHPh. In: Journal of the Chemical Society, Chemical Communications. 1984 ; No. 17. pp. 1172-1174.

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