A three-dimensional porous and magnetic framework constructed from {Cu 4(μ4-Cl)}+7 clusters and 4-(1H-Tetrazol-5yl)-benzoic acid, (Me2NH2)[Cu 4Cl(tba)4(H2O)4].2DMF

Wayne Ouellette; Hongxue Liu; Kelly Whitenack; Charles J. O'Connor; Jon Zubieta

doi:10.1021/cg900734d

A three-dimensional porous and magnetic framework constructed from {Cu ₄(μ₄-Cl)}⁺⁷ clusters and 4-(1H-Tetrazol-5yl)-benzoic acid, (Me₂NH₂)[Cu ₄Cl(tba)₄(H₂O)₄].2DMF

Wayne Ouellette, Hongxue Liu, Kelly Whitenack, Charles J. O'Connor, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

The hydrothermal reaction of CUCl₂.2H₂O and 4-(1H tetrazol-5-yl)-benzoic acid (H₂tba) in the presence of excess HCl yielded the three-dimensional material (Me₂NH₂)[Cu ₄Cl(tba)₄(H₂O)₄]-2DMF. The structure is constructed from (Cu₄(μ₄-Cl)(H₂O) ₄}⁷⁺ clusters linked through tba^2- ligands into an open framework with 57% void volume. The microporosity and magnetic properties of the material were investigated.

Original language	English (US)
Pages (from-to)	4258-4261
Number of pages	4
Journal	Crystal Growth and Design
Volume	9
Issue number	10
DOIs	https://doi.org/10.1021/cg900734d
State	Published - Oct 7 2009

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1021/cg900734d

Cite this

@article{eb912769078e4493b6505b3e424dff7f,

title = "A three-dimensional porous and magnetic framework constructed from {Cu 4(μ4-Cl)}+7 clusters and 4-(1H-Tetrazol-5yl)-benzoic acid, (Me2NH2)[Cu 4Cl(tba)4(H2O)4].2DMF",

abstract = "The hydrothermal reaction of CUCl2.2H2O and 4-(1H tetrazol-5-yl)-benzoic acid (H2tba) in the presence of excess HCl yielded the three-dimensional material (Me2NH2)[Cu 4Cl(tba)4(H2O)4]-2DMF. The structure is constructed from (Cu4(μ4-Cl)(H2O) 4}7+ clusters linked through tba2- ligands into an open framework with 57% void volume. The microporosity and magnetic properties of the material were investigated.",

author = "Wayne Ouellette and Hongxue Liu and Kelly Whitenack and O'Connor, {Charles J.} and Jon Zubieta",

year = "2009",

month = oct,

day = "7",

doi = "10.1021/cg900734d",

language = "English (US)",

volume = "9",

pages = "4258--4261",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "10",

}

TY - JOUR

T1 - A three-dimensional porous and magnetic framework constructed from {Cu 4(μ4-Cl)}+7 clusters and 4-(1H-Tetrazol-5yl)-benzoic acid, (Me2NH2)[Cu 4Cl(tba)4(H2O)4].2DMF

AU - Ouellette, Wayne

AU - Liu, Hongxue

AU - Whitenack, Kelly

AU - O'Connor, Charles J.

AU - Zubieta, Jon

PY - 2009/10/7

Y1 - 2009/10/7

N2 - The hydrothermal reaction of CUCl2.2H2O and 4-(1H tetrazol-5-yl)-benzoic acid (H2tba) in the presence of excess HCl yielded the three-dimensional material (Me2NH2)[Cu 4Cl(tba)4(H2O)4]-2DMF. The structure is constructed from (Cu4(μ4-Cl)(H2O) 4}7+ clusters linked through tba2- ligands into an open framework with 57% void volume. The microporosity and magnetic properties of the material were investigated.

AB - The hydrothermal reaction of CUCl2.2H2O and 4-(1H tetrazol-5-yl)-benzoic acid (H2tba) in the presence of excess HCl yielded the three-dimensional material (Me2NH2)[Cu 4Cl(tba)4(H2O)4]-2DMF. The structure is constructed from (Cu4(μ4-Cl)(H2O) 4}7+ clusters linked through tba2- ligands into an open framework with 57% void volume. The microporosity and magnetic properties of the material were investigated.

UR - http://www.scopus.com/inward/record.url?scp=70350230020&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=70350230020&partnerID=8YFLogxK

U2 - 10.1021/cg900734d

DO - 10.1021/cg900734d

M3 - Article

AN - SCOPUS:70350230020

SN - 1528-7483

VL - 9

SP - 4258

EP - 4261

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 10

ER -

A three-dimensional porous and magnetic framework constructed from {Cu ₄(μ₄-Cl)}⁺⁷ clusters and 4-(1H-Tetrazol-5yl)-benzoic acid, (Me₂NH₂)[Cu ₄Cl(tba)₄(H₂O)₄].2DMF

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this