A three-dimensional porous and magnetic framework constructed from {Cu 44-Cl)}+7 clusters and 4-(1H-Tetrazol-5yl)-benzoic acid, (Me2NH2)[Cu 4Cl(tba)4(H2O)4].2DMF

Wayne Ouellette, Hongxue Liu, Kelly Whitenack, Charles J. O'Connor, Jon Zubieta

Research output: Contribution to journalArticle

22 Scopus citations

Abstract

The hydrothermal reaction of CUCl2.2H2O and 4-(1H tetrazol-5-yl)-benzoic acid (H2tba) in the presence of excess HCl yielded the three-dimensional material (Me2NH2)[Cu 4Cl(tba)4(H2O)4]-2DMF. The structure is constructed from (Cu44-Cl)(H2O) 4}7+ clusters linked through tba2- ligands into an open framework with 57% void volume. The microporosity and magnetic properties of the material were investigated.

Original languageEnglish (US)
Pages (from-to)4258-4261
Number of pages4
JournalCrystal Growth and Design
Volume9
Issue number10
DOIs
StatePublished - Oct 7 2009

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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