A three dimensional organic-inorganic composite material constructed from cobalt-3,3'-bipyridyl networks linked through tetravanadate clusters: [{Co(3,3'-bpy)2}2V4O12]

Robert L. LaDuca Jr.; Claudia Brodkin; Robert C. Finn; Jon Zubieta

doi:10.1016/S1387-7003(00)00066-6

A three dimensional organic-inorganic composite material constructed from cobalt-3,3'-bipyridyl networks linked through tetravanadate clusters: [{Co(3,3'-bpy)₂}₂V₄O₁₂]

Robert L. LaDuca Jr., Claudia Brodkin, Robert C. Finn, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

61 Scopus citations

Abstract

The hydrothermal reaction of CoCl₂·6H₂O, 3,3'-bipyridine and NaVO₃ in water at 160°C for 48 h yields the three-dimensional bimetallic oxide [{Co(3,3'-bpy)₂}₂V₄O₁₂] (1). The structure of 1 consists of two-dimensional {Co(3,3'-bpy)₂}(n)(2n+) networks, linked through cyclic tetranuclear {V₄O₁₂}^4- clusters into a three-dimensional covalently linked assembly. Crystal data for C₂₀H₁₆CoN₄O₆V₂ (1): monoclinic, P2₁/n, a = 9.9794(6), b = 16.129(1), c = 13.4190(8) Å, β = 93.039(1)°, V = 2156.9(2) Å³, Z = 4, D(calc) = 1.753 g/cm³. (C) 2000 Elsevier Science S.A.

Original language	English (US)
Pages (from-to)	248-250
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	3
Issue number	5
DOIs	https://doi.org/10.1016/S1387-7003(00)00066-6
State	Published - 2000

Keywords

Bimetallic oxide
Composite material
Crystal structures
Hydrothermal synthesis
Modular synthesis

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S1387-7003(00)00066-6

Cite this

A three dimensional organic-inorganic composite material constructed from cobalt-3,3'-bipyridyl networks linked through tetravanadate clusters: [{Co(3,3'-bpy)₂}₂V₄O₁₂]. / L. LaDuca Jr., Robert; Brodkin, Claudia; Finn, Robert C. et al.
In: Inorganic Chemistry Communications, Vol. 3, No. 5, 2000, p. 248-250.

Research output: Contribution to journal › Article › peer-review

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title = "A three dimensional organic-inorganic composite material constructed from cobalt-3,3'-bipyridyl networks linked through tetravanadate clusters: [{Co(3,3'-bpy)2}2V4O12]",

abstract = "The hydrothermal reaction of CoCl2·6H2O, 3,3'-bipyridine and NaVO3 in water at 160°C for 48 h yields the three-dimensional bimetallic oxide [{Co(3,3'-bpy)2}2V4O12] (1). The structure of 1 consists of two-dimensional {Co(3,3'-bpy)2}(n)(2n+) networks, linked through cyclic tetranuclear {V4O12}4- clusters into a three-dimensional covalently linked assembly. Crystal data for C20H16CoN4O6V2 (1): monoclinic, P21/n, a = 9.9794(6), b = 16.129(1), c = 13.4190(8) {\AA}, β = 93.039(1)°, V = 2156.9(2) {\AA}3, Z = 4, D(calc) = 1.753 g/cm3. (C) 2000 Elsevier Science S.A.",

keywords = "Bimetallic oxide, Composite material, Crystal structures, Hydrothermal synthesis, Modular synthesis",

author = "{L. LaDuca Jr.}, Robert and Claudia Brodkin and Finn, {Robert C.} and Jon Zubieta",

note = "Funding Information: This work was supported by NSF grant CHE 9617232. The work at King's College was supported by an award from Research Corporation. Copyright: Copyright 2007 Elsevier B.V., All rights reserved.",

year = "2000",

doi = "10.1016/S1387-7003(00)00066-6",

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T2 - [{Co(3,3'-bpy)2}2V4O12]

AU - L. LaDuca Jr., Robert

AU - Brodkin, Claudia

AU - Finn, Robert C.

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by NSF grant CHE 9617232. The work at King's College was supported by an award from Research Corporation. Copyright: Copyright 2007 Elsevier B.V., All rights reserved.

PY - 2000

Y1 - 2000

N2 - The hydrothermal reaction of CoCl2·6H2O, 3,3'-bipyridine and NaVO3 in water at 160°C for 48 h yields the three-dimensional bimetallic oxide [{Co(3,3'-bpy)2}2V4O12] (1). The structure of 1 consists of two-dimensional {Co(3,3'-bpy)2}(n)(2n+) networks, linked through cyclic tetranuclear {V4O12}4- clusters into a three-dimensional covalently linked assembly. Crystal data for C20H16CoN4O6V2 (1): monoclinic, P21/n, a = 9.9794(6), b = 16.129(1), c = 13.4190(8) Å, β = 93.039(1)°, V = 2156.9(2) Å3, Z = 4, D(calc) = 1.753 g/cm3. (C) 2000 Elsevier Science S.A.

AB - The hydrothermal reaction of CoCl2·6H2O, 3,3'-bipyridine and NaVO3 in water at 160°C for 48 h yields the three-dimensional bimetallic oxide [{Co(3,3'-bpy)2}2V4O12] (1). The structure of 1 consists of two-dimensional {Co(3,3'-bpy)2}(n)(2n+) networks, linked through cyclic tetranuclear {V4O12}4- clusters into a three-dimensional covalently linked assembly. Crystal data for C20H16CoN4O6V2 (1): monoclinic, P21/n, a = 9.9794(6), b = 16.129(1), c = 13.4190(8) Å, β = 93.039(1)°, V = 2156.9(2) Å3, Z = 4, D(calc) = 1.753 g/cm3. (C) 2000 Elsevier Science S.A.

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