A thermally and hydrolytically stable microporous framework exhibiting single-chain magnetism: Structure and properties of [Co2(H 0.67bdt)3]·20H2O

Wayne Ouellette, Andrey V. Prosvirin, Kelly Whitenack, Kim R. Dunbar, Jon Zubieta

Research output: Contribution to journalArticle

155 Scopus citations

Abstract

Fixing a hole: Hydrothermal chemistry has been exploited in the preparation of a 3D framework material exhibiting 48 % accessible void volume and 1.5 % hydrogen uptake by weight at 120 kPa (see picture). The title compound also exhibits single-chain magnetic behavior and reversible changes in magnetic properties upon solvation and desolvation. (Figure Presented).

Original languageEnglish (US)
Pages (from-to)2140-2143
Number of pages4
JournalAngewandte Chemie - International Edition
Volume48
Issue number12
DOIs
StatePublished - Mar 9 2009

Keywords

  • Cobalt
  • Hydrothermal synthesis
  • Magnetic properties
  • Organic-inorganic hybrid composites

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Fingerprint Dive into the research topics of 'A thermally and hydrolytically stable microporous framework exhibiting single-chain magnetism: Structure and properties of [Co<sub>2</sub>(H <sub>0.67</sub>bdt)<sub>3</sub>]·20H<sub>2</sub>O'. Together they form a unique fingerprint.

  • Cite this