A thermally and hydrolytically stable microporous framework exhibiting single-chain magnetism: Structure and properties of [Co2(H 0.67bdt)3]·20H2O

Wayne Ouellette; Andrey V. Prosvirin; Kelly Whitenack; Kim R. Dunbar; Jon Zubieta

doi:10.1002/anie.200804805

A thermally and hydrolytically stable microporous framework exhibiting single-chain magnetism: Structure and properties of [Co₂(H _0.67bdt)₃]·20H₂O

Wayne Ouellette, Andrey V. Prosvirin, Kelly Whitenack, Kim R. Dunbar, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

162 Scopus citations

Abstract

Fixing a hole: Hydrothermal chemistry has been exploited in the preparation of a 3D framework material exhibiting 48 % accessible void volume and 1.5 % hydrogen uptake by weight at 120 kPa (see picture). The title compound also exhibits single-chain magnetic behavior and reversible changes in magnetic properties upon solvation and desolvation. (Figure Presented).

Original language	English (US)
Pages (from-to)	2140-2143
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	12
DOIs	https://doi.org/10.1002/anie.200804805
State	Published - Mar 9 2009

Keywords

Cobalt
Hydrothermal synthesis
Magnetic properties
Organic-inorganic hybrid composites

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/anie.200804805

Cite this

A thermally and hydrolytically stable microporous framework exhibiting single-chain magnetism: Structure and properties of [Co₂(H _0.67bdt)₃]·20H₂O. / Ouellette, Wayne; Prosvirin, Andrey V.; Whitenack, Kelly et al.
In: Angewandte Chemie - International Edition, Vol. 48, No. 12, 09.03.2009, p. 2140-2143.

Research output: Contribution to journal › Article › peer-review

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