A self-assembled, metallo-organic supramolecular frequency doubler

Luke A. Burke; Grazia Gonella; Fenton Heirtzler; Hai Lung Dai; Stephanie Jones; Jon Zubieta; Alex J. Roche

doi:10.1039/c2cc16199k

A self-assembled, metallo-organic supramolecular frequency doubler

Luke A. Burke, Grazia Gonella, Fenton Heirtzler, Hai Lung Dai, Stephanie Jones, Jon Zubieta, Alex J. Roche

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The dimeric self-assembly program of a new, multidentate ligand with cuprous ions overcomes crystal packing forces, which leads to C_i symmetry in the solid state, to form a no less than partially C₂-symmetric structure in solution. The resulting tetranitro-substituted dicopper(i) metallocyclophane displays an exceptionally strong second harmonic frequency response (β = (3000 ± 600) × 10⁻³⁰ esu for a fundamental at 800 nm).

Original language	English (US)
Pages (from-to)	1000-1002
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	7
DOIs	https://doi.org/10.1039/c2cc16199k
State	Published - Jan 3 2012

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c2cc16199k

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AU - Heirtzler, Fenton

AU - Dai, Hai Lung

AU - Jones, Stephanie

AU - Zubieta, Jon

AU - Roche, Alex J.

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AB - The dimeric self-assembly program of a new, multidentate ligand with cuprous ions overcomes crystal packing forces, which leads to Ci symmetry in the solid state, to form a no less than partially C2-symmetric structure in solution. The resulting tetranitro-substituted dicopper(i) metallocyclophane displays an exceptionally strong second harmonic frequency response (β = (3000 ± 600) × 10−30 esu for a fundamental at 800 nm).

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A self-assembled, metallo-organic supramolecular frequency doubler

Abstract

ASJC Scopus subject areas

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