A self-assembled, metallo-organic supramolecular frequency doubler

Luke A. Burke, Grazia Gonella, Fenton Heirtzler, Hai Lung Dai, Stephanie Jones, Jon A Zubieta, Alex J. Roche

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The dimeric self-assembly program of a new, multidentate ligand with cuprous ions overcomes crystal packing forces, which leads to C i symmetry in the solid state, to form a no less than partially C 2-symmetric structure in solution. The resulting tetranitro- substituted dicopper(i) metallocyclophane displays an exceptionally strong second harmonic frequency response (β = (3000 ± 600) × 10 -30 esu for a fundamental at 800 nm).

Original languageEnglish (US)
Pages (from-to)1000-1002
Number of pages3
JournalChemical Communications
Volume48
Issue number7
DOIs
StatePublished - Jan 25 2012

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Program assemblers
Frequency doublers
Crystal symmetry
Self assembly
Frequency response
Ligands
Crystals
Ions
cuprous ion

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Burke, L. A., Gonella, G., Heirtzler, F., Dai, H. L., Jones, S., Zubieta, J. A., & Roche, A. J. (2012). A self-assembled, metallo-organic supramolecular frequency doubler. Chemical Communications, 48(7), 1000-1002. https://doi.org/10.1039/c2cc16199k

A self-assembled, metallo-organic supramolecular frequency doubler. / Burke, Luke A.; Gonella, Grazia; Heirtzler, Fenton; Dai, Hai Lung; Jones, Stephanie; Zubieta, Jon A; Roche, Alex J.

In: Chemical Communications, Vol. 48, No. 7, 25.01.2012, p. 1000-1002.

Research output: Contribution to journalArticle

Burke, LA, Gonella, G, Heirtzler, F, Dai, HL, Jones, S, Zubieta, JA & Roche, AJ 2012, 'A self-assembled, metallo-organic supramolecular frequency doubler', Chemical Communications, vol. 48, no. 7, pp. 1000-1002. https://doi.org/10.1039/c2cc16199k
Burke LA, Gonella G, Heirtzler F, Dai HL, Jones S, Zubieta JA et al. A self-assembled, metallo-organic supramolecular frequency doubler. Chemical Communications. 2012 Jan 25;48(7):1000-1002. https://doi.org/10.1039/c2cc16199k
Burke, Luke A. ; Gonella, Grazia ; Heirtzler, Fenton ; Dai, Hai Lung ; Jones, Stephanie ; Zubieta, Jon A ; Roche, Alex J. / A self-assembled, metallo-organic supramolecular frequency doubler. In: Chemical Communications. 2012 ; Vol. 48, No. 7. pp. 1000-1002.
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