A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting

Aysun Bulut; Michael Wörle; Yunus Zorlu; Erdogan Kirpi; Huseyin Kurt; Jon Zubieta; Simon Grabowsky; Jens Beckmann; Gündoǧ Yücesan

doi:10.1107/S2052520617000245

A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting

Aysun Bulut, Michael Wörle, Yunus Zorlu, Erdogan Kirpi, Huseyin Kurt, Jon Zubieta, Simon Grabowsky, Jens Beckmann, Gündoǧ Yücesan

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The reaction of appropriate copper and vanadium salts with tetratopic methane tetra-p-phenylphosphonic acid (MTPPA) in the presence of 2,2':6':2''-terpyridine (terpy) yielded the three-dimensional bimetallic copper vanadium phosphonate framework[{Cu(terpy)}₄Cu(VO₂)₄(MTPPA-H)₂]·4H₂O (1). Terpy has no net contribution to the three-dimensional structure providing a potential platform for void space formation via mold-casting. The structure was characterized by single-crystal X-ray diffraction and thermogravimetric analysis (TGA). Magnetic measurements were performed using a SQUID magnetometer. The crystal structure of the methanol solvate of the free ligand, MTPPA·MeOH, was analysed using Hirshfeld surfaces and fingerprint plots.A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting is reported.

Original language	English (US)
Pages (from-to)	296-303
Number of pages	8
Journal	Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials
Volume	73
Issue number	2
DOIs	https://doi.org/10.1107/S2052520617000245
State	Published - Apr 1 2017

Keywords

Hirshfeld surfaces
bimetallic Cu-V frameworks
metal organic frameworks (MOFs)
organophosphonate complexes
void space formation

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Metals and Alloys
Materials Chemistry

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title = "A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting",

abstract = "The reaction of appropriate copper and vanadium salts with tetratopic methane tetra-p-phenylphosphonic acid (MTPPA) in the presence of 2,2':6':2''-terpyridine (terpy) yielded the three-dimensional bimetallic copper vanadium phosphonate framework[{Cu(terpy)}4Cu(VO2)4(MTPPA-H)2]·4H2O (1). Terpy has no net contribution to the three-dimensional structure providing a potential platform for void space formation via mold-casting. The structure was characterized by single-crystal X-ray diffraction and thermogravimetric analysis (TGA). Magnetic measurements were performed using a SQUID magnetometer. The crystal structure of the methanol solvate of the free ligand, MTPPA·MeOH, was analysed using Hirshfeld surfaces and fingerprint plots.A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting is reported.",

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AU - Bulut, Aysun

AU - Wörle, Michael

AU - Zorlu, Yunus

AU - Kirpi, Erdogan

AU - Kurt, Huseyin

AU - Zubieta, Jon

AU - Grabowsky, Simon

AU - Beckmann, Jens

AU - Yücesan, Gündoǧ

N1 - Publisher Copyright: © International Union of Crystallography, 2017.

PY - 2017/4/1

Y1 - 2017/4/1

N2 - The reaction of appropriate copper and vanadium salts with tetratopic methane tetra-p-phenylphosphonic acid (MTPPA) in the presence of 2,2':6':2''-terpyridine (terpy) yielded the three-dimensional bimetallic copper vanadium phosphonate framework[{Cu(terpy)}4Cu(VO2)4(MTPPA-H)2]·4H2O (1). Terpy has no net contribution to the three-dimensional structure providing a potential platform for void space formation via mold-casting. The structure was characterized by single-crystal X-ray diffraction and thermogravimetric analysis (TGA). Magnetic measurements were performed using a SQUID magnetometer. The crystal structure of the methanol solvate of the free ligand, MTPPA·MeOH, was analysed using Hirshfeld surfaces and fingerprint plots.A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting is reported.

AB - The reaction of appropriate copper and vanadium salts with tetratopic methane tetra-p-phenylphosphonic acid (MTPPA) in the presence of 2,2':6':2''-terpyridine (terpy) yielded the three-dimensional bimetallic copper vanadium phosphonate framework[{Cu(terpy)}4Cu(VO2)4(MTPPA-H)2]·4H2O (1). Terpy has no net contribution to the three-dimensional structure providing a potential platform for void space formation via mold-casting. The structure was characterized by single-crystal X-ray diffraction and thermogravimetric analysis (TGA). Magnetic measurements were performed using a SQUID magnetometer. The crystal structure of the methanol solvate of the free ligand, MTPPA·MeOH, was analysed using Hirshfeld surfaces and fingerprint plots.A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting is reported.

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KW - metal organic frameworks (MOFs)

KW - organophosphonate complexes

KW - void space formation

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A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting

Abstract

Keywords

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