A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting

Aysun Bulut; Michael Wörle; Yunus Zorlu; Erdogan Kirpi; Huseyin Kurt; Jon Zubieta; Simon Grabowsky; Jens Beckmann; Gündoǧ Yücesan

doi:10.1107/S2052520617000245

A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting

Aysun Bulut, Michael Wörle, Yunus Zorlu, Erdogan Kirpi, Huseyin Kurt, Jon Zubieta, Simon Grabowsky, Jens Beckmann, Gündoǧ Yücesan

Department of Chemistry

Research output: Contribution to journal › Article

10 Scopus citations

Abstract

The reaction of appropriate copper and vanadium salts with tetratopic methane tetra-p-phenylphosphonic acid (MTPPA) in the presence of 2,2':6':2''-terpyridine (terpy) yielded the three-dimensional bimetallic copper vanadium phosphonate framework[{Cu(terpy)}₄Cu(VO₂)₄(MTPPA-H)₂]·4H₂O (1). Terpy has no net contribution to the three-dimensional structure providing a potential platform for void space formation via mold-casting. The structure was characterized by single-crystal X-ray diffraction and thermogravimetric analysis (TGA). Magnetic measurements were performed using a SQUID magnetometer. The crystal structure of the methanol solvate of the free ligand, MTPPA·MeOH, was analysed using Hirshfeld surfaces and fingerprint plots.A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting is reported.

Original language	English (US)
Pages (from-to)	296-303
Number of pages	8
Journal	Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials
Volume	73
Issue number	2
DOIs	https://doi.org/10.1107/S2052520617000245
State	Published - Apr 1 2017

Keywords

bimetallic Cu-V frameworks
Hirshfeld surfaces
metal organic frameworks (MOFs)
organophosphonate complexes
void space formation

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Metals and Alloys
Materials Chemistry

Access to Document

10.1107/S2052520617000245

Fingerprint Dive into the research topics of 'A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting'. Together they form a unique fingerprint.

Cite this

Bulut, A., Wörle, M., Zorlu, Y., Kirpi, E., Kurt, H., Zubieta, J., Grabowsky, S., Beckmann, J., & Yücesan, G. (2017). A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting. Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 73(2), 296-303. https://doi.org/10.1107/S2052520617000245

A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting. / Bulut, Aysun; Wörle, Michael; Zorlu, Yunus; Kirpi, Erdogan; Kurt, Huseyin; Zubieta, Jon; Grabowsky, Simon; Beckmann, Jens; Yücesan, Gündoǧ.

In: Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, Vol. 73, No. 2, 01.04.2017, p. 296-303.

Research output: Contribution to journal › Article

Bulut, Aysun ; Wörle, Michael ; Zorlu, Yunus ; Kirpi, Erdogan ; Kurt, Huseyin ; Zubieta, Jon ; Grabowsky, Simon ; Beckmann, Jens ; Yücesan, Gündoǧ. / A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting. In: Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials. 2017 ; Vol. 73, No. 2. pp. 296-303.

@article{d9ad5a3dfd6e479c92da5f6981e8680b,

title = "A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting",

abstract = "The reaction of appropriate copper and vanadium salts with tetratopic methane tetra-p-phenylphosphonic acid (MTPPA) in the presence of 2,2':6':2''-terpyridine (terpy) yielded the three-dimensional bimetallic copper vanadium phosphonate framework[{Cu(terpy)}4Cu(VO2)4(MTPPA-H)2]·4H2O (1). Terpy has no net contribution to the three-dimensional structure providing a potential platform for void space formation via mold-casting. The structure was characterized by single-crystal X-ray diffraction and thermogravimetric analysis (TGA). Magnetic measurements were performed using a SQUID magnetometer. The crystal structure of the methanol solvate of the free ligand, MTPPA·MeOH, was analysed using Hirshfeld surfaces and fingerprint plots.A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting is reported.",

keywords = "bimetallic Cu-V frameworks, Hirshfeld surfaces, metal organic frameworks (MOFs), organophosphonate complexes, void space formation",

author = "Aysun Bulut and Michael W{\"o}rle and Yunus Zorlu and Erdogan Kirpi and Huseyin Kurt and Jon Zubieta and Simon Grabowsky and Jens Beckmann and G{\"u}ndoǧ Y{\"u}cesan",

year = "2017",

month = apr,

day = "1",

doi = "10.1107/S2052520617000245",

language = "English (US)",

volume = "73",

pages = "296--303",

journal = "Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials",

issn = "2052-5192",

publisher = "John Wiley and Sons Inc.",

number = "2",

}

TY - JOUR

T1 - A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting

AU - Bulut, Aysun

AU - Wörle, Michael

AU - Zorlu, Yunus

AU - Kirpi, Erdogan

AU - Kurt, Huseyin

AU - Zubieta, Jon

AU - Grabowsky, Simon

AU - Beckmann, Jens

AU - Yücesan, Gündoǧ

PY - 2017/4/1

Y1 - 2017/4/1

N2 - The reaction of appropriate copper and vanadium salts with tetratopic methane tetra-p-phenylphosphonic acid (MTPPA) in the presence of 2,2':6':2''-terpyridine (terpy) yielded the three-dimensional bimetallic copper vanadium phosphonate framework[{Cu(terpy)}4Cu(VO2)4(MTPPA-H)2]·4H2O (1). Terpy has no net contribution to the three-dimensional structure providing a potential platform for void space formation via mold-casting. The structure was characterized by single-crystal X-ray diffraction and thermogravimetric analysis (TGA). Magnetic measurements were performed using a SQUID magnetometer. The crystal structure of the methanol solvate of the free ligand, MTPPA·MeOH, was analysed using Hirshfeld surfaces and fingerprint plots.A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting is reported.

AB - The reaction of appropriate copper and vanadium salts with tetratopic methane tetra-p-phenylphosphonic acid (MTPPA) in the presence of 2,2':6':2''-terpyridine (terpy) yielded the three-dimensional bimetallic copper vanadium phosphonate framework[{Cu(terpy)}4Cu(VO2)4(MTPPA-H)2]·4H2O (1). Terpy has no net contribution to the three-dimensional structure providing a potential platform for void space formation via mold-casting. The structure was characterized by single-crystal X-ray diffraction and thermogravimetric analysis (TGA). Magnetic measurements were performed using a SQUID magnetometer. The crystal structure of the methanol solvate of the free ligand, MTPPA·MeOH, was analysed using Hirshfeld surfaces and fingerprint plots.A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting is reported.

KW - bimetallic Cu-V frameworks

KW - Hirshfeld surfaces

KW - metal organic frameworks (MOFs)

KW - organophosphonate complexes

KW - void space formation

UR - http://www.scopus.com/inward/record.url?scp=85017187346&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85017187346&partnerID=8YFLogxK

U2 - 10.1107/S2052520617000245

DO - 10.1107/S2052520617000245

M3 - Article

C2 - 28362294

AN - SCOPUS:85017187346

VL - 73

SP - 296

EP - 303

JO - Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials

JF - Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials

SN - 2052-5192

IS - 2

ER -