A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting

Aysun Bulut, Michael Wörle, Yunus Zorlu, Erdogan Kirpi, Huseyin Kurt, Jon Zubieta, Simon Grabowsky, Jens Beckmann, Gündoǧ Yücesan

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The reaction of appropriate copper and vanadium salts with tetratopic methane tetra-p-phenylphosphonic acid (MTPPA) in the presence of 2,2':6':2''-terpyridine (terpy) yielded the three-dimensional bimetallic copper vanadium phosphonate framework[{Cu(terpy)}4Cu(VO2)4(MTPPA-H)2]·4H2O (1). Terpy has no net contribution to the three-dimensional structure providing a potential platform for void space formation via mold-casting. The structure was characterized by single-crystal X-ray diffraction and thermogravimetric analysis (TGA). Magnetic measurements were performed using a SQUID magnetometer. The crystal structure of the methanol solvate of the free ligand, MTPPA·MeOH, was analysed using Hirshfeld surfaces and fingerprint plots.A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting is reported.

Original languageEnglish (US)
Pages (from-to)296-303
Number of pages8
JournalActa Crystallographica Section B: Structural Science, Crystal Engineering and Materials
Volume73
Issue number2
DOIs
StatePublished - Apr 1 2017

Fingerprint

Organophosphonates
Vanadium
Methane
vanadium
Copper
voids
Casting
methane
platforms
copper
acids
Acids
SQUIDs
Magnetic variables measurement
Magnetometers
magnetometers
X ray diffraction analysis
magnetic measurement
Methanol
Thermogravimetric analysis

Keywords

  • bimetallic Cu-V frameworks
  • Hirshfeld surfaces
  • metal organic frameworks (MOFs)
  • organophosphonate complexes
  • void space formation

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Atomic and Molecular Physics, and Optics
  • Metals and Alloys
  • Materials Chemistry

Cite this

A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting. / Bulut, Aysun; Wörle, Michael; Zorlu, Yunus; Kirpi, Erdogan; Kurt, Huseyin; Zubieta, Jon; Grabowsky, Simon; Beckmann, Jens; Yücesan, Gündoǧ.

In: Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, Vol. 73, No. 2, 01.04.2017, p. 296-303.

Research output: Contribution to journalArticle

Bulut, Aysun ; Wörle, Michael ; Zorlu, Yunus ; Kirpi, Erdogan ; Kurt, Huseyin ; Zubieta, Jon ; Grabowsky, Simon ; Beckmann, Jens ; Yücesan, Gündoǧ. / A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting. In: Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials. 2017 ; Vol. 73, No. 2. pp. 296-303.
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