A one-dimensional coordination polymer incorporating a less common bipyridine isomer: Catena-poly[[bis(acetato-κO)aquacopper(II)]-μ-3, 3′-bipyridine-κN:N′]

Matthew Desciak, Randy S. Rarig, Jon Zubieta, Robert L. LaDuca

Research output: Contribution to journalArticle

Abstract

The title compound, [Cu(CH3COO)2(C10H 8N2)(H2O)]n, is a one-dimensional coordination polymer containing square-pyramidally coordinated Cu bound to two N atoms from two 3,3′-bipyridine molecules, two O atoms from two distinct monodentate acetate anions, and one O atom from an aqua ligand. Anti-conformation 3,3′-bipyridine units link the CuII atoms into chain motifs that run parallel to the a crystal axis. These arrange into layers parallel to the ac crystal plane through supramolecular hydrogen bonding.

Original languageEnglish (US)
Pages (from-to)m434-m437
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number2
DOIs
StatePublished - Feb 1 2007

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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