A novel beryllium thiolate resulting from N-Si bond cleavage: Liberation of ammonia in the reaction of Be[N(SiMe3)2]2 with HSPh

Scott Chadwick; Ulrich Englich; Karin Ruhlandt-Senge

doi:10.1002/(SICI)1521-3773(19981116)37:21<3007::AID-ANIE3007>3.0.CO;2-R

A novel beryllium thiolate resulting from N-Si bond cleavage: Liberation of ammonia in the reaction of Be[N(SiMe₃)₂]₂ with HSPh

Scott Chadwick, Ulrich Englich, Karin Ruhlandt-Senge

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

A side reaction leads to the product. In the synthesis of [{Be(SPh)₂(py)(NH₃)}₂{[18]crown-6}] (1, py = pyridine) from [Be{N(SiMe₃)₂}₂] and HSPh, the coordinated ammonia molecules (see the structure of 1 in the picture) are formed in a competing reaction between liberated hexamethyldisilazane and the thiol.

Original language	English (US)
Pages (from-to)	3007-3009
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	37
Issue number	21
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19981116)37:21<3007::AID-ANIE3007>3.0.CO;2-R
State	Published - Nov 16 1998

Keywords

Alkaline earth metals
Amides
Hydrogen bonds
Protonations
S ligands

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/(SICI)1521-3773(19981116)37:21<3007::AID-ANIE3007>3.0.CO;2-R

Cite this

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title = "A novel beryllium thiolate resulting from N-Si bond cleavage: Liberation of ammonia in the reaction of Be[N(SiMe3)2]2 with HSPh",

abstract = "A side reaction leads to the product. In the synthesis of [{Be(SPh)2(py)(NH3)}2{[18]crown-6}] (1, py = pyridine) from [Be{N(SiMe3)2}2] and HSPh, the coordinated ammonia molecules (see the structure of 1 in the picture) are formed in a competing reaction between liberated hexamethyldisilazane and the thiol.",

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AU - Englich, Ulrich

AU - Ruhlandt-Senge, Karin

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AB - A side reaction leads to the product. In the synthesis of [{Be(SPh)2(py)(NH3)}2{[18]crown-6}] (1, py = pyridine) from [Be{N(SiMe3)2}2] and HSPh, the coordinated ammonia molecules (see the structure of 1 in the picture) are formed in a competing reaction between liberated hexamethyldisilazane and the thiol.

KW - Alkaline earth metals

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KW - Hydrogen bonds

KW - Protonations

KW - S ligands

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