A new class of organic-inorganic hybrid materials: Hydrothermal synthesis and structural characterization of bimetallic organophosphonate oxide phases of the Mo/Cu/O/RPO32- family

R. C. Finn; J. Zubieta

doi:10.1021/ic0100018

A new class of organic-inorganic hybrid materials: Hydrothermal synthesis and structural characterization of bimetallic organophosphonate oxide phases of the Mo/Cu/O/RPO₃^2- family

R. C. Finn, J. Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

157 Scopus citations

Abstract

The hydrothermal reactions of Cu(SO₄)·5H₂O, MoO₂, 1,10-phenanthroline, and the appropriate organodiphosphonate ligand yield organic-inorganic hybrid materials with one- or two-dimensional structures; the presence of cluster building blocks is illustrated by the structure of [{Cu(H₂O)₂(o-phen)}{Cu(o-phen)₂}(Mo ₅O₁₅)(O₃PCH₂CH₂CH ₂PO₃)].

Original language	English (US)
Pages (from-to)	2466-2467
Number of pages	2
Journal	Inorganic Chemistry
Volume	40
Issue number	11
DOIs	https://doi.org/10.1021/ic0100018
State	Published - May 21 2001

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "A new class of organic-inorganic hybrid materials: Hydrothermal synthesis and structural characterization of bimetallic organophosphonate oxide phases of the Mo/Cu/O/RPO32- family",

abstract = "The hydrothermal reactions of Cu(SO4)·5H2O, MoO2, 1,10-phenanthroline, and the appropriate organodiphosphonate ligand yield organic-inorganic hybrid materials with one- or two-dimensional structures; the presence of cluster building blocks is illustrated by the structure of [{Cu(H2O)2(o-phen)}{Cu(o-phen)2}(Mo 5O15)(O3PCH2CH2CH 2PO3)].",

author = "Finn, {R. C.} and J. Zubieta",

year = "2001",

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doi = "10.1021/ic0100018",

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T2 - Hydrothermal synthesis and structural characterization of bimetallic organophosphonate oxide phases of the Mo/Cu/O/RPO32- family

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AU - Zubieta, J.

PY - 2001/5/21

Y1 - 2001/5/21

N2 - The hydrothermal reactions of Cu(SO4)·5H2O, MoO2, 1,10-phenanthroline, and the appropriate organodiphosphonate ligand yield organic-inorganic hybrid materials with one- or two-dimensional structures; the presence of cluster building blocks is illustrated by the structure of [{Cu(H2O)2(o-phen)}{Cu(o-phen)2}(Mo 5O15)(O3PCH2CH2CH 2PO3)].

AB - The hydrothermal reactions of Cu(SO4)·5H2O, MoO2, 1,10-phenanthroline, and the appropriate organodiphosphonate ligand yield organic-inorganic hybrid materials with one- or two-dimensional structures; the presence of cluster building blocks is illustrated by the structure of [{Cu(H2O)2(o-phen)}{Cu(o-phen)2}(Mo 5O15)(O3PCH2CH2CH 2PO3)].

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A new class of organic-inorganic hybrid materials: Hydrothermal synthesis and structural characterization of bimetallic organophosphonate oxide phases of the Mo/Cu/O/RPO₃^2- family

Abstract

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