TY - JOUR
T1 - A monomeric molybdenum thiolato-complex with a chelated η6-arene ligand. The preparation and structure of [Mo{(η6-Ph)PhC6H3S-2,6}(SC 6H3Ph2-2,6)(CO)]
AU - Bishop, Peter T.
AU - Dilworth, Jonathan R.
AU - Zubieta, Jon A.
PY - 1985
Y1 - 1985
N2 - Sodium 2,6-diphenylbenzenethiolate reacts with [MoBr2(CO) 4] to give the chelated η6-arene complex [Mo{(η6-Ph)PhC6H3S-2,6}(SC 6H3Ph2-2,6)(CO)] (1) in good yield, the X-ray crystal structure of which reveals a distorted 'piano-stool' geometry.
AB - Sodium 2,6-diphenylbenzenethiolate reacts with [MoBr2(CO) 4] to give the chelated η6-arene complex [Mo{(η6-Ph)PhC6H3S-2,6}(SC 6H3Ph2-2,6)(CO)] (1) in good yield, the X-ray crystal structure of which reveals a distorted 'piano-stool' geometry.
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U2 - 10.1039/C39850000257
DO - 10.1039/C39850000257
M3 - Article
AN - SCOPUS:37049099457
SN - 0022-4936
SP - 257
EP - 259
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 5
ER -