A hybrid bimetallic complex from regioselective in situ ligand oxidation: Poly[(μ-Β-octamolybdato-k2 O:O)bis-[μ-4-(2-pyrid-yl) pyridinium-3-olato-k3 N,O:O]bis-[4-(2-pyrid-yl)pyridinium-3-olato- k2 N,O]dicopper(II)]

Caleb H. Springsteen; Randy S. Rarig; Jon Zubieta; Robert L. Laduca

doi:10.1107/S1600536807009282

A hybrid bimetallic complex from regioselective in situ ligand oxidation: Poly[(μ-Β-octamolybdato-k² O:O)bis-[μ-4-(2-pyrid-yl) pyridinium-3-olato-k³ N,O:O]bis-[4-(2-pyrid-yl)pyridinium-3-olato- k² N,O]dicopper(II)]

Caleb H. Springsteen, Randy S. Rarig, Jon Zubieta, Robert L. Laduca

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [Cu2(C10H8N2O)4(Β-Mo8O26)] n , is a one-dimensional coordination polymer containing octa-hedrally coordinated Cu^II atoms, each of which is bound to three O atoms and two N atoms from three distinct regioselectively oxidized 2,4′-bipyridinium ligands and one O atom from a centrosymmetric Β-octa-molybdate anion. The 4′-position N atoms within the ligands, as quaternary N atoms, are uncoordinated. [Cu2(2′-O^--2,4′-bpyH⁺)4] ⁴⁺ dimeric cations are linked through exobidentate Β-octa-molybdate anions into polymeric chains running along the [011] direction. N - H⋯O and C - H⋯O inter-actions connect adjacent chains into a three-dimensional network.

Original language	English (US)
Pages (from-to)	m933-m935
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	4
DOIs	https://doi.org/10.1107/S1600536807009282
State	Published - Mar 2 2007

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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Springsteen, C. H., Rarig, R. S., Zubieta, J., & Laduca, R. L. (2007). A hybrid bimetallic complex from regioselective in situ ligand oxidation: Poly[(μ-Β-octamolybdato-k² O:O)bis-[μ-4-(2-pyrid-yl) pyridinium-3-olato-k³ N,O:O]bis-[4-(2-pyrid-yl)pyridinium-3-olato- k² N,O]dicopper(II)]. Acta Crystallographica Section E: Structure Reports Online, 63(4), m933-m935. https://doi.org/10.1107/S1600536807009282

A hybrid bimetallic complex from regioselective in situ ligand oxidation: Poly[(μ-Β-octamolybdato-k² O:O)bis-[μ-4-(2-pyrid-yl) pyridinium-3-olato-k³ N,O:O]bis-[4-(2-pyrid-yl)pyridinium-3-olato- k² N,O]dicopper(II)]. / Springsteen, Caleb H.; Rarig, Randy S.; Zubieta, Jon et al.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 63, No. 4, 02.03.2007, p. m933-m935.

Research output: Contribution to journal › Article › peer-review

Springsteen, CH, Rarig, RS, Zubieta, J & Laduca, RL 2007, 'A hybrid bimetallic complex from regioselective in situ ligand oxidation: Poly[(μ-Β-octamolybdato-k² O:O)bis-[μ-4-(2-pyrid-yl) pyridinium-3-olato-k³ N,O:O]bis-[4-(2-pyrid-yl)pyridinium-3-olato- k² N,O]dicopper(II)]', Acta Crystallographica Section E: Structure Reports Online, vol. 63, no. 4, pp. m933-m935. https://doi.org/10.1107/S1600536807009282

Springsteen CH, Rarig RS, Zubieta J, Laduca RL. A hybrid bimetallic complex from regioselective in situ ligand oxidation: Poly[(μ-Β-octamolybdato-k² O:O)bis-[μ-4-(2-pyrid-yl) pyridinium-3-olato-k³ N,O:O]bis-[4-(2-pyrid-yl)pyridinium-3-olato- k² N,O]dicopper(II)]. Acta Crystallographica Section E: Structure Reports Online. 2007 Mar 2;63(4):m933-m935. doi: 10.1107/S1600536807009282

Springsteen, Caleb H. ; Rarig, Randy S. ; Zubieta, Jon et al. / A hybrid bimetallic complex from regioselective in situ ligand oxidation : Poly[(μ-Β-octamolybdato-k² O:O)bis-[μ-4-(2-pyrid-yl) pyridinium-3-olato-k³ N,O:O]bis-[4-(2-pyrid-yl)pyridinium-3-olato- k² N,O]dicopper(II)]. In: Acta Crystallographica Section E: Structure Reports Online. 2007 ; Vol. 63, No. 4. pp. m933-m935.

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abstract = "The title compound, [Cu2(C10H8N2O)4(Β-Mo8O26)] n , is a one-dimensional coordination polymer containing octa-hedrally coordinated CuII atoms, each of which is bound to three O atoms and two N atoms from three distinct regioselectively oxidized 2,4′-bipyridinium ligands and one O atom from a centrosymmetric Β-octa-molybdate anion. The 4′-position N atoms within the ligands, as quaternary N atoms, are uncoordinated. [Cu2(2′-O--2,4′-bpyH+)4] 4+ dimeric cations are linked through exobidentate Β-octa-molybdate anions into polymeric chains running along the [011] direction. N - H⋯O and C - H⋯O inter-actions connect adjacent chains into a three-dimensional network.",

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N2 - The title compound, [Cu2(C10H8N2O)4(Β-Mo8O26)] n , is a one-dimensional coordination polymer containing octa-hedrally coordinated CuII atoms, each of which is bound to three O atoms and two N atoms from three distinct regioselectively oxidized 2,4′-bipyridinium ligands and one O atom from a centrosymmetric Β-octa-molybdate anion. The 4′-position N atoms within the ligands, as quaternary N atoms, are uncoordinated. [Cu2(2′-O--2,4′-bpyH+)4] 4+ dimeric cations are linked through exobidentate Β-octa-molybdate anions into polymeric chains running along the [011] direction. N - H⋯O and C - H⋯O inter-actions connect adjacent chains into a three-dimensional network.

AB - The title compound, [Cu2(C10H8N2O)4(Β-Mo8O26)] n , is a one-dimensional coordination polymer containing octa-hedrally coordinated CuII atoms, each of which is bound to three O atoms and two N atoms from three distinct regioselectively oxidized 2,4′-bipyridinium ligands and one O atom from a centrosymmetric Β-octa-molybdate anion. The 4′-position N atoms within the ligands, as quaternary N atoms, are uncoordinated. [Cu2(2′-O--2,4′-bpyH+)4] 4+ dimeric cations are linked through exobidentate Β-octa-molybdate anions into polymeric chains running along the [011] direction. N - H⋯O and C - H⋯O inter-actions connect adjacent chains into a three-dimensional network.

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