The title compound, [Cu2(C10H8N2O)4(Β-Mo8O26)] n , is a one-dimensional coordination polymer containing octa-hedrally coordinated CuII atoms, each of which is bound to three O atoms and two N atoms from three distinct regioselectively oxidized 2,4′-bipyridinium ligands and one O atom from a centrosymmetric Β-octa-molybdate anion. The 4′-position N atoms within the ligands, as quaternary N atoms, are uncoordinated. [Cu2(2′-O--2,4′-bpyH+)4] 4+ dimeric cations are linked through exobidentate Β-octa-molybdate anions into polymeric chains running along the  direction. N - H⋯O and C - H⋯O inter-actions connect adjacent chains into a three-dimensional network.
|Original language||English (US)|
|Journal||Acta Crystallographica Section E: Structure Reports Online|
|State||Published - Mar 2 2007|
ASJC Scopus subject areas
- Materials Science(all)
- Condensed Matter Physics