TY - JOUR
T1 - A coordination polymer with conformationally distinct layers
T2 - Poly[(μ-1,3-di-4-pyridylpropane-κ2N:N′) bis(μ3-thiocyanato-κ3N,S:S)dicopper(I)]
AU - Trovitch, Ryan J.
AU - Rarig, Randy S.
AU - Zubieta, Jon A.
AU - LaDuca, Robert L.
PY - 2007/2
Y1 - 2007/2
N2 - The title compound, [Cu2(SCN)2(C13H 14N2)]n, is a two-dimensional coordination polymer containing tetrahedrally coordinated Cu1 atoms bound to one N atom from a 1,3-di-4-pyridylpropane molecule, and one N and two S atoms from three distinct μ3-thiocyanate anions. The resulting [Cu 2(SCN)2] staircase motifs align parallel to the b crystal axis and link through tethering 1,3-di-4-pyridylpropane ligands into layers parallel to the bc crystal plane. Distinct layers with subtly different conformations stack in a BAA′B′ pattern, where the B A and A′B′ double slabs are related by an inversion center.
AB - The title compound, [Cu2(SCN)2(C13H 14N2)]n, is a two-dimensional coordination polymer containing tetrahedrally coordinated Cu1 atoms bound to one N atom from a 1,3-di-4-pyridylpropane molecule, and one N and two S atoms from three distinct μ3-thiocyanate anions. The resulting [Cu 2(SCN)2] staircase motifs align parallel to the b crystal axis and link through tethering 1,3-di-4-pyridylpropane ligands into layers parallel to the bc crystal plane. Distinct layers with subtly different conformations stack in a BAA′B′ pattern, where the B A and A′B′ double slabs are related by an inversion center.
UR - http://www.scopus.com/inward/record.url?scp=33846993398&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33846993398&partnerID=8YFLogxK
U2 - 10.1107/S1600536806055395
DO - 10.1107/S1600536806055395
M3 - Article
AN - SCOPUS:33846993398
SN - 1600-5368
VL - 63
SP - m339-m341
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 2
ER -