Abstract
The complexes [MoO(SR)4]- (R = aryl) and [MoO{S(CH2)nS}2]- (n = 2 or 3) can be prepared by reaction of an MoVI butanediolato-complex with thiolate anion in methanol. The complexes [MoO(SPh)4]- react with R′2NNH2 [R′2 = Me2 or (CH2)5] in refluxing CH3CN to give [Mo(NNR′2)O(SPh)3]-. Crystal Data for [PPh4] [Mo(NNMe2)O(SC6H5)3]·(C 2H5)2O: space group Pbca, a = 12.789(4), b = 19.375(3), c = 36.941(3) Å, Z = 8.3 225 Independent reflections with I > 3σ(I) gave R = 0.076. The geometry is essentially square-pyramidal with an apical oxo-group and the NNMe2 group in the basal plane. Although the MO-N and N-N distances of 1.821(9) and 1.292(14) Å respectively are analogous to other hydrazido(2-) complexes, the Mo-N-NMe2 system is anomalously bent with MO-N-N = 152.5(10)°.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 2295-2298 |
| Number of pages | 4 |
| Journal | Journal of the Chemical Society - Dalton Transactions |
| Issue number | 11 |
| DOIs | |
| State | Published - 1982 |
| Externally published | Yes |
Fingerprint
ASJC Scopus subject areas
- Chemistry(all)
Cite this
A convenient route to complexes of the type [MoO(SR)4]-(R = aryl) and [MoO{S(CH2)nS}2]- (n = 2 or 3) preparation and crystal structure of [PPh4][Mo(NNMe2)O(SC6H5) 3]·(C2H5)2O. / Burt, R. J.; Dilworth, J. R.; Leigh, G. J.; Zubieta, Jon A.
In: Journal of the Chemical Society - Dalton Transactions, No. 11, 1982, p. 2295-2298.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - A convenient route to complexes of the type [MoO(SR)4]-(R = aryl) and [MoO{S(CH2)nS}2]- (n = 2 or 3) preparation and crystal structure of [PPh4][Mo(NNMe2)O(SC6H5) 3]·(C2H5)2O
AU - Burt, R. J.
AU - Dilworth, J. R.
AU - Leigh, G. J.
AU - Zubieta, Jon A
PY - 1982
Y1 - 1982
N2 - The complexes [MoO(SR)4]- (R = aryl) and [MoO{S(CH2)nS}2]- (n = 2 or 3) can be prepared by reaction of an MoVI butanediolato-complex with thiolate anion in methanol. The complexes [MoO(SPh)4]- react with R′2NNH2 [R′2 = Me2 or (CH2)5] in refluxing CH3CN to give [Mo(NNR′2)O(SPh)3]-. Crystal Data for [PPh4] [Mo(NNMe2)O(SC6H5)3]·(C 2H5)2O: space group Pbca, a = 12.789(4), b = 19.375(3), c = 36.941(3) Å, Z = 8.3 225 Independent reflections with I > 3σ(I) gave R = 0.076. The geometry is essentially square-pyramidal with an apical oxo-group and the NNMe2 group in the basal plane. Although the MO-N and N-N distances of 1.821(9) and 1.292(14) Å respectively are analogous to other hydrazido(2-) complexes, the Mo-N-NMe2 system is anomalously bent with MO-N-N = 152.5(10)°.
AB - The complexes [MoO(SR)4]- (R = aryl) and [MoO{S(CH2)nS}2]- (n = 2 or 3) can be prepared by reaction of an MoVI butanediolato-complex with thiolate anion in methanol. The complexes [MoO(SPh)4]- react with R′2NNH2 [R′2 = Me2 or (CH2)5] in refluxing CH3CN to give [Mo(NNR′2)O(SPh)3]-. Crystal Data for [PPh4] [Mo(NNMe2)O(SC6H5)3]·(C 2H5)2O: space group Pbca, a = 12.789(4), b = 19.375(3), c = 36.941(3) Å, Z = 8.3 225 Independent reflections with I > 3σ(I) gave R = 0.076. The geometry is essentially square-pyramidal with an apical oxo-group and the NNMe2 group in the basal plane. Although the MO-N and N-N distances of 1.821(9) and 1.292(14) Å respectively are analogous to other hydrazido(2-) complexes, the Mo-N-NMe2 system is anomalously bent with MO-N-N = 152.5(10)°.
UR - http://www.scopus.com/inward/record.url?scp=37049107311&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=37049107311&partnerID=8YFLogxK
U2 - 10.1039/DT9820002295
DO - 10.1039/DT9820002295
M3 - Article
AN - SCOPUS:37049107311
SP - 2295
EP - 2298
JO - Dalton Transactions
JF - Dalton Transactions
SN - 0300-9246
IS - 11
ER -