A butadienediyl-bridged diiron compound in three oxidation levels

Beth A. Etzenhouser, Qin Chen, Michael Sponsler

Research output: Contribution to journalArticle

53 Citations (Scopus)

Abstract

A conjugated dinuclear iron complex, [CpFe-(dppm)]2(μ-CH=CHCH=CH), has been prepared and oxidized to radical cation and dication species. The butadienediyl bridge apparently allows for strong electronic coupling between the iron atoms, as determined by cyclic voltammetry, electronic absorption spectroscopy, and an X-ray crystal structure determination on the dication.

Original languageEnglish (US)
Pages (from-to)4176-4178
Number of pages3
JournalOrganometallics
Volume13
Issue number11
StatePublished - 1994

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Iron
methylidyne
iron
Oxidation
oxidation
Absorption spectroscopy
electronics
Cyclic voltammetry
Cations
absorption spectroscopy
Crystal structure
cations
X rays
Atoms
crystal structure
atoms
x rays

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

A butadienediyl-bridged diiron compound in three oxidation levels. / Etzenhouser, Beth A.; Chen, Qin; Sponsler, Michael.

In: Organometallics, Vol. 13, No. 11, 1994, p. 4176-4178.

Research output: Contribution to journalArticle

Etzenhouser, BA, Chen, Q & Sponsler, M 1994, 'A butadienediyl-bridged diiron compound in three oxidation levels', Organometallics, vol. 13, no. 11, pp. 4176-4178.
Etzenhouser, Beth A. ; Chen, Qin ; Sponsler, Michael. / A butadienediyl-bridged diiron compound in three oxidation levels. In: Organometallics. 1994 ; Vol. 13, No. 11. pp. 4176-4178.
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