A Butadienediyl-Bridged Diiron Compound in Three Oxidation Levels

Beth A. Etzenhouser; Qin Chen; Michael B. Sponsler

doi:10.1021/om00023a019

A Butadienediyl-Bridged Diiron Compound in Three Oxidation Levels

Beth A. Etzenhouser, Qin Chen, Michael B. Sponsler

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

A conjugated dinuclear iron complex, [CpFe-(dppm)]₂(μ-CH═CHCH═CH), has been prepared and oxidized to radical cation and dication species. The butadienediyl bridge apparently allows for strong electronic coupling between the iron atoms, as determined by cyclic voltammetry, electronic absorption spectroscopy, and an X-ray crystal structure determination on the dication.

Original language	English (US)
Pages (from-to)	4176-4178
Number of pages	3
Journal	Organometallics
Volume	13
Issue number	11
DOIs	https://doi.org/10.1021/om00023a019
State	Published - Nov 1 1994

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om00023a019

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title = "A Butadienediyl-Bridged Diiron Compound in Three Oxidation Levels",

abstract = "A conjugated dinuclear iron complex, [CpFe-(dppm)]2(μ-CH═CHCH═CH), has been prepared and oxidized to radical cation and dication species. The butadienediyl bridge apparently allows for strong electronic coupling between the iron atoms, as determined by cyclic voltammetry, electronic absorption spectroscopy, and an X-ray crystal structure determination on the dication.",

author = "Etzenhouser, {Beth A.} and Qin Chen and Sponsler, {Michael B.}",

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AU - Sponsler, Michael B.

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N2 - A conjugated dinuclear iron complex, [CpFe-(dppm)]2(μ-CH═CHCH═CH), has been prepared and oxidized to radical cation and dication species. The butadienediyl bridge apparently allows for strong electronic coupling between the iron atoms, as determined by cyclic voltammetry, electronic absorption spectroscopy, and an X-ray crystal structure determination on the dication.

AB - A conjugated dinuclear iron complex, [CpFe-(dppm)]2(μ-CH═CHCH═CH), has been prepared and oxidized to radical cation and dication species. The butadienediyl bridge apparently allows for strong electronic coupling between the iron atoms, as determined by cyclic voltammetry, electronic absorption spectroscopy, and an X-ray crystal structure determination on the dication.

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A Butadienediyl-Bridged Diiron Compound in Three Oxidation Levels

Abstract

ASJC Scopus subject areas

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