A Butadienediyl-Bridged Diiron Compound in Three Oxidation Levels

Beth A. Etzenhouser, Qin Chen, Michael B. Sponsler

Research output: Contribution to journalArticle

54 Scopus citations

Abstract

A conjugated dinuclear iron complex, [CpFe-(dppm)]2(μ-CH═CHCH═CH), has been prepared and oxidized to radical cation and dication species. The butadienediyl bridge apparently allows for strong electronic coupling between the iron atoms, as determined by cyclic voltammetry, electronic absorption spectroscopy, and an X-ray crystal structure determination on the dication.

Original languageEnglish (US)
Pages (from-to)4176-4178
Number of pages3
JournalOrganometallics
Volume13
Issue number11
DOIs
StatePublished - Nov 1 1994

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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