A building block approach to the synthesis of organic–inorganic oxide materials: The hydrothermal synthesis and network structure of [(Ni4(tpypyz)3)(Mo5O

Eric Burkholder; Vladimir Golub; Charles J. O’Connor; Jon Zubieta

doi:10.1039/b303659f

A building block approach to the synthesis of organic–inorganic oxide materials: The hydrothermal synthesis and network structure of [(Ni₄(tpypyz)₃)(Mo₅O

Eric Burkholder, Vladimir Golub, Charles J. O’Connor, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

108 Scopus citations

Abstract

The hydrothermal reaction of MoO₃, [Ni(CH₃CO₂)₂]·4H₂O, tpypyz, ethylenediphosphonic acid and water yields the 2D material [(Ni₄(tpypyz)₃)(Mo₅O₁₅(O₃PCH₂CH₂PO₃))₂]·23H₂O (1·23H₂O), constructed from (Mo₅O₁₅(O₃PCH₂CH₂PO₃))⁴⁻ clusters linked in one-dimension through the ethylene tethers of the diphosphonate component; these molybdodiphosphonate chains are in turn linked into a 2D network through the tetranuclear secondary metal–ligand subunit (Ni₄(tpypyz)₃)⁸⁺.

Original language	English (US)
Pages (from-to)	2128-2129
Number of pages	2
Journal	Chemical Communications
Volume	3
Issue number	17
DOIs	https://doi.org/10.1039/b303659f
State	Published - 2003

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "A building block approach to the synthesis of organic–inorganic oxide materials: The hydrothermal synthesis and network structure of [(Ni4(tpypyz)3)(Mo5O",

abstract = "The hydrothermal reaction of MoO3, [Ni(CH3CO2)2]·4H2O, tpypyz, ethylenediphosphonic acid and water yields the 2D material [(Ni4(tpypyz)3)(Mo5O15(O3PCH2CH2PO3))2]·23H2O (1·23H2O), constructed from (Mo5O15(O3PCH2CH2PO3))4− clusters linked in one-dimension through the ethylene tethers of the diphosphonate component; these molybdodiphosphonate chains are in turn linked into a 2D network through the tetranuclear secondary metal–ligand subunit (Ni4(tpypyz)3)8+.",

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T2 - The hydrothermal synthesis and network structure of [(Ni4(tpypyz)3)(Mo5O

AU - Burkholder, Eric

AU - Golub, Vladimir

AU - O’Connor, Charles J.

AU - Zubieta, Jon

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AB - The hydrothermal reaction of MoO3, [Ni(CH3CO2)2]·4H2O, tpypyz, ethylenediphosphonic acid and water yields the 2D material [(Ni4(tpypyz)3)(Mo5O15(O3PCH2CH2PO3))2]·23H2O (1·23H2O), constructed from (Mo5O15(O3PCH2CH2PO3))4− clusters linked in one-dimension through the ethylene tethers of the diphosphonate component; these molybdodiphosphonate chains are in turn linked into a 2D network through the tetranuclear secondary metal–ligand subunit (Ni4(tpypyz)3)8+.

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A building block approach to the synthesis of organic–inorganic oxide materials: The hydrothermal synthesis and network structure of [(Ni₄(tpypyz)₃)(Mo₅O

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