A building block approach to the synthesis of organic–inorganic oxide materials: The hydrothermal synthesis and network structure of [(Ni4(tpypyz)3)(Mo5O

Eric Burkholder, Vladimir Golub, Charles J. O’Connor, Jon Zubieta

Research output: Contribution to journalArticle

105 Scopus citations

Abstract

The hydrothermal reaction of MoO3, [Ni(CH3CO2)2]·4H2O, tpypyz, ethylenediphosphonic acid and water yields the 2D material [(Ni4(tpypyz)3)(Mo5O15(O3PCH2CH2PO3))2]·23H2O (1·23H2O), constructed from (Mo5O15(O3PCH2CH2PO3))4− clusters linked in one-dimension through the ethylene tethers of the diphosphonate component; these molybdodiphosphonate chains are in turn linked into a 2D network through the tetranuclear secondary metal–ligand subunit (Ni4(tpypyz)3)8+.

Original languageEnglish (US)
Pages (from-to)2128-2129
Number of pages2
JournalChemical Communications
Volume3
Issue number17
DOIs
StatePublished - Jan 1 2003

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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