A binuclear vanadium oxyfluoride: Di-μ-oxido-bis[fluoridooxido(1,10- phenanthroline)vanadium(V)]

Paul Deburgomaster, Jon A Zubieta

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The title compound, [V2F2O4(C 12H8N2)2], is a centrosymmetric binuclear vanadium(V) species with the metal ions in a distorted octa-hedral environment. The symmetry-equivalent VV atoms exhibit coordination geometries defined by cis-terminal fluoride and oxide groups, unsymmetrically bridging oxide groups and the N-atom donors of the phenanthroline ligands. The crystal packing is stabilized by weak inter-molecular C - H⋯O and C - H⋯F hydrogen bonds.

Original languageEnglish (US)
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number10
DOIs
StatePublished - Oct 2010

Fingerprint

oxyfluorides
Vanadium
Oxides
vanadium
Atoms
Phenanthrolines
oxides
Fluorides
Metal ions
atoms
fluorides
metal ions
Hydrogen bonds
Ligands
hydrogen bonds
Crystals
ligands
Geometry
symmetry
geometry

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

@article{8ee0ccf4d6b242728dac7b8e5f646116,
title = "A binuclear vanadium oxyfluoride: Di-μ-oxido-bis[fluoridooxido(1,10- phenanthroline)vanadium(V)]",
abstract = "The title compound, [V2F2O4(C 12H8N2)2], is a centrosymmetric binuclear vanadium(V) species with the metal ions in a distorted octa-hedral environment. The symmetry-equivalent VV atoms exhibit coordination geometries defined by cis-terminal fluoride and oxide groups, unsymmetrically bridging oxide groups and the N-atom donors of the phenanthroline ligands. The crystal packing is stabilized by weak inter-molecular C - H⋯O and C - H⋯F hydrogen bonds.",
author = "Paul Deburgomaster and Zubieta, {Jon A}",
year = "2010",
month = "10",
doi = "10.1107/S1600536810037232",
language = "English (US)",
volume = "66",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "10",

}

TY - JOUR

T1 - A binuclear vanadium oxyfluoride

T2 - Di-μ-oxido-bis[fluoridooxido(1,10- phenanthroline)vanadium(V)]

AU - Deburgomaster, Paul

AU - Zubieta, Jon A

PY - 2010/10

Y1 - 2010/10

N2 - The title compound, [V2F2O4(C 12H8N2)2], is a centrosymmetric binuclear vanadium(V) species with the metal ions in a distorted octa-hedral environment. The symmetry-equivalent VV atoms exhibit coordination geometries defined by cis-terminal fluoride and oxide groups, unsymmetrically bridging oxide groups and the N-atom donors of the phenanthroline ligands. The crystal packing is stabilized by weak inter-molecular C - H⋯O and C - H⋯F hydrogen bonds.

AB - The title compound, [V2F2O4(C 12H8N2)2], is a centrosymmetric binuclear vanadium(V) species with the metal ions in a distorted octa-hedral environment. The symmetry-equivalent VV atoms exhibit coordination geometries defined by cis-terminal fluoride and oxide groups, unsymmetrically bridging oxide groups and the N-atom donors of the phenanthroline ligands. The crystal packing is stabilized by weak inter-molecular C - H⋯O and C - H⋯F hydrogen bonds.

UR - http://www.scopus.com/inward/record.url?scp=77957832083&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77957832083&partnerID=8YFLogxK

U2 - 10.1107/S1600536810037232

DO - 10.1107/S1600536810037232

M3 - Article

C2 - 21587442

AN - SCOPUS:77957832083

VL - 66

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 10

ER -