A binuclear vanadium oxyfluoride: Di-μ-oxido-bis[fluoridooxido(1,10- phenanthroline)vanadium(V)]

Paul Deburgomaster, Jon Zubieta

Research output: Contribution to journalArticle

6 Scopus citations

Abstract

The title compound, [V2F2O4(C 12H8N2)2], is a centrosymmetric binuclear vanadium(V) species with the metal ions in a distorted octa-hedral environment. The symmetry-equivalent VV atoms exhibit coordination geometries defined by cis-terminal fluoride and oxide groups, unsymmetrically bridging oxide groups and the N-atom donors of the phenanthroline ligands. The crystal packing is stabilized by weak inter-molecular C - H⋯O and C - H⋯F hydrogen bonds.

Original languageEnglish (US)
Pages (from-to)m1303
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number10
DOIs
StatePublished - Oct 2010

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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