TY - JOUR
T1 - A binuclear vanadium oxyfluoride
T2 - Di-μ-oxido-bis[(2,2′-bipyridyl) fluorido-oxidovanadium(V)]
AU - Deburgomaster, Paul
AU - Zubieta, Jon
PY - 2010/9
Y1 - 2010/9
N2 - The title compound, [V2F2O4(C 10H8N)2], is a centrosymmetric binuclear vanadium(V) species with the metal ions in a distorted octa-hedral environment. The coordination geometries of the symmetry-equivalent VV atoms are defined by cis-terminal fluoride and oxide groups, unsymmetrically bridging oxide groups and the N-atom donors of the bipyridyl ligand. The crystal packing is stabilized by weak inter-molecular C-H⋯O and C-H⋯F hydrogen bonds.
AB - The title compound, [V2F2O4(C 10H8N)2], is a centrosymmetric binuclear vanadium(V) species with the metal ions in a distorted octa-hedral environment. The coordination geometries of the symmetry-equivalent VV atoms are defined by cis-terminal fluoride and oxide groups, unsymmetrically bridging oxide groups and the N-atom donors of the bipyridyl ligand. The crystal packing is stabilized by weak inter-molecular C-H⋯O and C-H⋯F hydrogen bonds.
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U2 - 10.1107/S1600536810031302
DO - 10.1107/S1600536810031302
M3 - Article
C2 - 21588507
AN - SCOPUS:77956330033
SN - 1600-5368
VL - 66
SP - m1091
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 9
ER -