A binuclear vanadium oxyfluoride: Di-μ-oxido-bis[(2,2′-bipyridyl) fluorido-oxidovanadium(V)]

Paul Deburgomaster, Jon A Zubieta

Research output: Contribution to journalArticle

Abstract

The title compound, [V2F2O4(C 10H8N)2], is a centrosymmetric binuclear vanadium(V) species with the metal ions in a distorted octa-hedral environment. The coordination geometries of the symmetry-equivalent VV atoms are defined by cis-terminal fluoride and oxide groups, unsymmetrically bridging oxide groups and the N-atom donors of the bipyridyl ligand. The crystal packing is stabilized by weak inter-molecular C-H⋯O and C-H⋯F hydrogen bonds.

Original languageEnglish (US)
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number9
DOIs
StatePublished - Sep 2010

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oxyfluorides
Vanadium
2,2'-Dipyridyl
Oxides
vanadium
Atoms
oxides
Fluorides
Metal ions
atoms
fluorides
metal ions
Hydrogen bonds
Ligands
hydrogen bonds
Crystals
ligands
Geometry
symmetry
geometry

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

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abstract = "The title compound, [V2F2O4(C 10H8N)2], is a centrosymmetric binuclear vanadium(V) species with the metal ions in a distorted octa-hedral environment. The coordination geometries of the symmetry-equivalent VV atoms are defined by cis-terminal fluoride and oxide groups, unsymmetrically bridging oxide groups and the N-atom donors of the bipyridyl ligand. The crystal packing is stabilized by weak inter-molecular C-H⋯O and C-H⋯F hydrogen bonds.",
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T2 - Di-μ-oxido-bis[(2,2′-bipyridyl) fluorido-oxidovanadium(V)]

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AU - Zubieta, Jon A

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N2 - The title compound, [V2F2O4(C 10H8N)2], is a centrosymmetric binuclear vanadium(V) species with the metal ions in a distorted octa-hedral environment. The coordination geometries of the symmetry-equivalent VV atoms are defined by cis-terminal fluoride and oxide groups, unsymmetrically bridging oxide groups and the N-atom donors of the bipyridyl ligand. The crystal packing is stabilized by weak inter-molecular C-H⋯O and C-H⋯F hydrogen bonds.

AB - The title compound, [V2F2O4(C 10H8N)2], is a centrosymmetric binuclear vanadium(V) species with the metal ions in a distorted octa-hedral environment. The coordination geometries of the symmetry-equivalent VV atoms are defined by cis-terminal fluoride and oxide groups, unsymmetrically bridging oxide groups and the N-atom donors of the bipyridyl ligand. The crystal packing is stabilized by weak inter-molecular C-H⋯O and C-H⋯F hydrogen bonds.

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