A binuclear molybdenum oxyfluoride: μ-oxido-bis-[(2,2′-bipyridyl) fluoridodioxidomolybdenum(VI)]

Paul Deburgomaster, Jon A Zubieta

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The title compound, [MO2F2O5(C 10H8N2)2], is a centrosymmetric binuclear molybdenum(VI) species with the metal atoms in a distorted octahedral environment. The coordination geometries of the symmetry-equivalent molybdenum sites are defined by the cis-terminal oxide groups and the N-atom donors of the bipyridyl ligand in the equatorial plane with axial F and bridging O atoms. The bridging O atom occupies a center of symmetry. The molecules stack in the a-axis direction, and the crystal packing is stabilized by weak intra- and intermolecular C - H⋯O and C - H⋯F hydrogen bonds.

Original languageEnglish (US)
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number8
DOIs
StatePublished - Aug 2010

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oxyfluorides
2,2'-Dipyridyl
Molybdenum
molybdenum
Atoms
atoms
symmetry
Oxides
Hydrogen bonds
Metals
Ligands
hydrogen bonds
Crystals
ligands
Molecules
oxides
Geometry
fluorine monoxide
geometry
metals

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

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abstract = "The title compound, [MO2F2O5(C 10H8N2)2], is a centrosymmetric binuclear molybdenum(VI) species with the metal atoms in a distorted octahedral environment. The coordination geometries of the symmetry-equivalent molybdenum sites are defined by the cis-terminal oxide groups and the N-atom donors of the bipyridyl ligand in the equatorial plane with axial F and bridging O atoms. The bridging O atom occupies a center of symmetry. The molecules stack in the a-axis direction, and the crystal packing is stabilized by weak intra- and intermolecular C - H⋯O and C - H⋯F hydrogen bonds.",
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AB - The title compound, [MO2F2O5(C 10H8N2)2], is a centrosymmetric binuclear molybdenum(VI) species with the metal atoms in a distorted octahedral environment. The coordination geometries of the symmetry-equivalent molybdenum sites are defined by the cis-terminal oxide groups and the N-atom donors of the bipyridyl ligand in the equatorial plane with axial F and bridging O atoms. The bridging O atom occupies a center of symmetry. The molecules stack in the a-axis direction, and the crystal packing is stabilized by weak intra- and intermolecular C - H⋯O and C - H⋯F hydrogen bonds.

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