TY - JOUR
T1 - A binuclear molybdenum oxyfluoride:μ-oxido-bis-[(2,2′-bipyridyl) fluoridodioxidomolybdenum(VI)]
AU - Deburgomaster, Paul
AU - Zubieta, Jon
PY - 2010/8
Y1 - 2010/8
N2 - The title compound, [MO2F2O5(C 10H8N2)2], is a centrosymmetric binuclear molybdenum(VI) species with the metal atoms in a distorted octahedral environment. The coordination geometries of the symmetry-equivalent molybdenum sites are defined by the cis-terminal oxide groups and the N-atom donors of the bipyridyl ligand in the equatorial plane with axial F and bridging O atoms. The bridging O atom occupies a center of symmetry. The molecules stack in the a-axis direction, and the crystal packing is stabilized by weak intra- and intermolecular C - H⋯O and C - H⋯F hydrogen bonds.
AB - The title compound, [MO2F2O5(C 10H8N2)2], is a centrosymmetric binuclear molybdenum(VI) species with the metal atoms in a distorted octahedral environment. The coordination geometries of the symmetry-equivalent molybdenum sites are defined by the cis-terminal oxide groups and the N-atom donors of the bipyridyl ligand in the equatorial plane with axial F and bridging O atoms. The bridging O atom occupies a center of symmetry. The molecules stack in the a-axis direction, and the crystal packing is stabilized by weak intra- and intermolecular C - H⋯O and C - H⋯F hydrogen bonds.
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U2 - 10.1107/S1600536810026383
DO - 10.1107/S1600536810026383
M3 - Article
C2 - 21588148
AN - SCOPUS:77956337301
SN - 1600-5368
VL - 66
SP - m909
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 8
ER -