A bimetallic oxide network constructed from oxomolybdoarsonate clusters and copper(II)-tetrapyridylpyrazine building blocks

Kari Darling; Eric M. Burkholder; Steven Pellizzeri; Max Nanao; Jon Zubieta

doi:10.1016/j.inoche.2011.07.020

A bimetallic oxide network constructed from oxomolybdoarsonate clusters and copper(II)-tetrapyridylpyrazine building blocks

Kari Darling, Eric M. Burkholder, Steven Pellizzeri, Max Nanao, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The hydrothermal reaction of Cu(CH₃CO₂) ₂•H₂O, MoO₃, tetrapyridylpyrazine (tpyprz), and 2-hydroxypropyl-1,3-diarsonic acid provided green crystals of the bimetallic oxide phase [{Cu₂(tpyprz)(H₂O)}Mo ₆O₁₈(H₂O){O₃AsCH₂CH(OH) CH₂AsO₃}]•5.5H₂O (1•5.5H ₂O). The two-dimensional structure of 1•5.5H₂O is constructed from {Mo₆O₁₈(H₂O)(O ₃AsR)₂}_n^{4n -} chains linked through {Cu₂(tpyprz)(H₂O)}⁴⁺ rods into a network. The hexanuclear molybdate ring consists of a tetrad of edge-sharing {MoO ₆} octahedra that adopt the corner-sharing mode to a diad of face-sharing Mo octahedra. Crystal data for C₂₇H₃₇As ₂Cu₂Mo₆N₆O_32.5: monoclinic P2₁/c, fw = 1818.18, a = 13.1304(9) Å, b = 21.701(1) Å, c = 17.408(1) Å, β = 100.046(1)°, V = 4884.2(6) Å³, Z = 4, Dcalc = 2.472 g cm^{- 3}, R₁ = 0.0669.

Original language	English (US)
Pages (from-to)	1745-1748
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	14
Issue number	11
DOIs	https://doi.org/10.1016/j.inoche.2011.07.020
State	Published - Nov 2011

Keywords

Bimetallic oxide
Copper-molybdodiarsonate material
Organic-inorganic hybrid material
X-ray structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.inoche.2011.07.020

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@article{7f7631c770bd4d07b6832b10fa7fce44,

title = "A bimetallic oxide network constructed from oxomolybdoarsonate clusters and copper(II)-tetrapyridylpyrazine building blocks",

abstract = "The hydrothermal reaction of Cu(CH3CO2) 2•H2O, MoO3, tetrapyridylpyrazine (tpyprz), and 2-hydroxypropyl-1,3-diarsonic acid provided green crystals of the bimetallic oxide phase [{Cu2(tpyprz)(H2O)}Mo 6O18(H2O){O3AsCH2CH(OH) CH2AsO3}]•5.5H2O (1•5.5H 2O). The two-dimensional structure of 1•5.5H2O is constructed from {Mo6O18(H2O)(O 3AsR)2}n4n - chains linked through {Cu2(tpyprz)(H2O)}4+ rods into a network. The hexanuclear molybdate ring consists of a tetrad of edge-sharing {MoO 6} octahedra that adopt the corner-sharing mode to a diad of face-sharing Mo octahedra. Crystal data for C27H37As 2Cu2Mo6N6O32.5: monoclinic P21/c, fw = 1818.18, a = 13.1304(9) {\AA}, b = 21.701(1) {\AA}, c = 17.408(1) {\AA}, β = 100.046(1)°, V = 4884.2(6) {\AA}3, Z = 4, Dcalc = 2.472 g cm- 3, R1 = 0.0669.",

keywords = "Bimetallic oxide, Copper-molybdodiarsonate material, Organic-inorganic hybrid material, X-ray structure",

author = "Kari Darling and Burkholder, {Eric M.} and Steven Pellizzeri and Max Nanao and Jon Zubieta",

note = "Funding Information: This work was supported by a grant from the National Science Foundation ( CHE0907787 ). ",

year = "2011",

month = nov,

doi = "10.1016/j.inoche.2011.07.020",

language = "English (US)",

volume = "14",

pages = "1745--1748",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier",

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TY - JOUR

T1 - A bimetallic oxide network constructed from oxomolybdoarsonate clusters and copper(II)-tetrapyridylpyrazine building blocks

AU - Darling, Kari

AU - Burkholder, Eric M.

AU - Pellizzeri, Steven

AU - Nanao, Max

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by a grant from the National Science Foundation ( CHE0907787 ).

PY - 2011/11

Y1 - 2011/11

N2 - The hydrothermal reaction of Cu(CH3CO2) 2•H2O, MoO3, tetrapyridylpyrazine (tpyprz), and 2-hydroxypropyl-1,3-diarsonic acid provided green crystals of the bimetallic oxide phase [{Cu2(tpyprz)(H2O)}Mo 6O18(H2O){O3AsCH2CH(OH) CH2AsO3}]•5.5H2O (1•5.5H 2O). The two-dimensional structure of 1•5.5H2O is constructed from {Mo6O18(H2O)(O 3AsR)2}n4n - chains linked through {Cu2(tpyprz)(H2O)}4+ rods into a network. The hexanuclear molybdate ring consists of a tetrad of edge-sharing {MoO 6} octahedra that adopt the corner-sharing mode to a diad of face-sharing Mo octahedra. Crystal data for C27H37As 2Cu2Mo6N6O32.5: monoclinic P21/c, fw = 1818.18, a = 13.1304(9) Å, b = 21.701(1) Å, c = 17.408(1) Å, β = 100.046(1)°, V = 4884.2(6) Å3, Z = 4, Dcalc = 2.472 g cm- 3, R1 = 0.0669.

AB - The hydrothermal reaction of Cu(CH3CO2) 2•H2O, MoO3, tetrapyridylpyrazine (tpyprz), and 2-hydroxypropyl-1,3-diarsonic acid provided green crystals of the bimetallic oxide phase [{Cu2(tpyprz)(H2O)}Mo 6O18(H2O){O3AsCH2CH(OH) CH2AsO3}]•5.5H2O (1•5.5H 2O). The two-dimensional structure of 1•5.5H2O is constructed from {Mo6O18(H2O)(O 3AsR)2}n4n - chains linked through {Cu2(tpyprz)(H2O)}4+ rods into a network. The hexanuclear molybdate ring consists of a tetrad of edge-sharing {MoO 6} octahedra that adopt the corner-sharing mode to a diad of face-sharing Mo octahedra. Crystal data for C27H37As 2Cu2Mo6N6O32.5: monoclinic P21/c, fw = 1818.18, a = 13.1304(9) Å, b = 21.701(1) Å, c = 17.408(1) Å, β = 100.046(1)°, V = 4884.2(6) Å3, Z = 4, Dcalc = 2.472 g cm- 3, R1 = 0.0669.

KW - Bimetallic oxide

KW - Copper-molybdodiarsonate material

KW - Organic-inorganic hybrid material

KW - X-ray structure

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U2 - 10.1016/j.inoche.2011.07.020

DO - 10.1016/j.inoche.2011.07.020

M3 - Article

AN - SCOPUS:80053573993

SN - 1387-7003

VL - 14

SP - 1745

EP - 1748

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 11

ER -

A bimetallic oxide network constructed from oxomolybdoarsonate clusters and copper(II)-tetrapyridylpyrazine building blocks

Abstract

Keywords

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