A bimetallic oxide network constructed from oxomolybdoarsonate clusters and copper(II)-tetrapyridylpyrazine building blocks

Kari Darling, Eric M. Burkholder, Steven Pellizzeri, Max Nanao, Jon A Zubieta

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The hydrothermal reaction of Cu(CH3CO2) 2•H2O, MoO3, tetrapyridylpyrazine (tpyprz), and 2-hydroxypropyl-1,3-diarsonic acid provided green crystals of the bimetallic oxide phase [{Cu2(tpyprz)(H2O)}Mo 6O18(H2O){O3AsCH2CH(OH) CH2AsO3}]•5.5H2O (1•5.5H 2O). The two-dimensional structure of 1•5.5H2O is constructed from {Mo6O18(H2O)(O 3AsR)2}n4n - chains linked through {Cu2(tpyprz)(H2O)}4+ rods into a network. The hexanuclear molybdate ring consists of a tetrad of edge-sharing {MoO 6} octahedra that adopt the corner-sharing mode to a diad of face-sharing Mo octahedra. Crystal data for C27H37As 2Cu2Mo6N6O32.5: monoclinic P21/c, fw = 1818.18, a = 13.1304(9) Å, b = 21.701(1) Å, c = 17.408(1) Å, β = 100.046(1)°, V = 4884.2(6) Å3, Z = 4, Dcalc = 2.472 g cm- 3, R1 = 0.0669.

Original languageEnglish (US)
Pages (from-to)1745-1748
Number of pages4
JournalInorganic Chemistry Communications
Volume14
Issue number11
DOIs
StatePublished - Nov 2011

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Oxides
Copper
copper
Crystals
oxides
molybdates
crystals
rods
acids
Acids
rings
molybdate
molybdenum trioxide

Keywords

  • Bimetallic oxide
  • Copper-molybdodiarsonate material
  • Organic-inorganic hybrid material
  • X-ray structure

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

A bimetallic oxide network constructed from oxomolybdoarsonate clusters and copper(II)-tetrapyridylpyrazine building blocks. / Darling, Kari; Burkholder, Eric M.; Pellizzeri, Steven; Nanao, Max; Zubieta, Jon A.

In: Inorganic Chemistry Communications, Vol. 14, No. 11, 11.2011, p. 1745-1748.

Research output: Contribution to journalArticle

Darling, Kari ; Burkholder, Eric M. ; Pellizzeri, Steven ; Nanao, Max ; Zubieta, Jon A. / A bimetallic oxide network constructed from oxomolybdoarsonate clusters and copper(II)-tetrapyridylpyrazine building blocks. In: Inorganic Chemistry Communications. 2011 ; Vol. 14, No. 11. pp. 1745-1748.
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abstract = "The hydrothermal reaction of Cu(CH3CO2) 2•H2O, MoO3, tetrapyridylpyrazine (tpyprz), and 2-hydroxypropyl-1,3-diarsonic acid provided green crystals of the bimetallic oxide phase [{Cu2(tpyprz)(H2O)}Mo 6O18(H2O){O3AsCH2CH(OH) CH2AsO3}]•5.5H2O (1•5.5H 2O). The two-dimensional structure of 1•5.5H2O is constructed from {Mo6O18(H2O)(O 3AsR)2}n4n - chains linked through {Cu2(tpyprz)(H2O)}4+ rods into a network. The hexanuclear molybdate ring consists of a tetrad of edge-sharing {MoO 6} octahedra that adopt the corner-sharing mode to a diad of face-sharing Mo octahedra. Crystal data for C27H37As 2Cu2Mo6N6O32.5: monoclinic P21/c, fw = 1818.18, a = 13.1304(9) {\AA}, b = 21.701(1) {\AA}, c = 17.408(1) {\AA}, β = 100.046(1)°, V = 4884.2(6) {\AA}3, Z = 4, Dcalc = 2.472 g cm- 3, R1 = 0.0669.",
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N2 - The hydrothermal reaction of Cu(CH3CO2) 2•H2O, MoO3, tetrapyridylpyrazine (tpyprz), and 2-hydroxypropyl-1,3-diarsonic acid provided green crystals of the bimetallic oxide phase [{Cu2(tpyprz)(H2O)}Mo 6O18(H2O){O3AsCH2CH(OH) CH2AsO3}]•5.5H2O (1•5.5H 2O). The two-dimensional structure of 1•5.5H2O is constructed from {Mo6O18(H2O)(O 3AsR)2}n4n - chains linked through {Cu2(tpyprz)(H2O)}4+ rods into a network. The hexanuclear molybdate ring consists of a tetrad of edge-sharing {MoO 6} octahedra that adopt the corner-sharing mode to a diad of face-sharing Mo octahedra. Crystal data for C27H37As 2Cu2Mo6N6O32.5: monoclinic P21/c, fw = 1818.18, a = 13.1304(9) Å, b = 21.701(1) Å, c = 17.408(1) Å, β = 100.046(1)°, V = 4884.2(6) Å3, Z = 4, Dcalc = 2.472 g cm- 3, R1 = 0.0669.

AB - The hydrothermal reaction of Cu(CH3CO2) 2•H2O, MoO3, tetrapyridylpyrazine (tpyprz), and 2-hydroxypropyl-1,3-diarsonic acid provided green crystals of the bimetallic oxide phase [{Cu2(tpyprz)(H2O)}Mo 6O18(H2O){O3AsCH2CH(OH) CH2AsO3}]•5.5H2O (1•5.5H 2O). The two-dimensional structure of 1•5.5H2O is constructed from {Mo6O18(H2O)(O 3AsR)2}n4n - chains linked through {Cu2(tpyprz)(H2O)}4+ rods into a network. The hexanuclear molybdate ring consists of a tetrad of edge-sharing {MoO 6} octahedra that adopt the corner-sharing mode to a diad of face-sharing Mo octahedra. Crystal data for C27H37As 2Cu2Mo6N6O32.5: monoclinic P21/c, fw = 1818.18, a = 13.1304(9) Å, b = 21.701(1) Å, c = 17.408(1) Å, β = 100.046(1)°, V = 4884.2(6) Å3, Z = 4, Dcalc = 2.472 g cm- 3, R1 = 0.0669.

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