A bimetallic oxide hybrid material constructed from a coordination complex polymer and molybdenum oxide subunits, [Ni(3,4′-bipyridine)2MoO4]·3H2O

Robert L. LaDuca; Matthew Desiak; Randy S. Rarig; Jon Zubieta

doi:10.1016/S0020-1693(02)00705-3

A bimetallic oxide hybrid material constructed from a coordination complex polymer and molybdenum oxide subunits, [Ni(3,4′-bipyridine)₂MoO₄]·3H₂O

Robert L. LaDuca, Matthew Desiak, Randy S. Rarig, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

The hydrothermal reaction of NiCl₂·6H₂O, MoO₃, 3,4′-bipyridine (3,4′-bpy) and H₂O in the mole ratio 1.0:1.0:2.1:1500 yields [Ni(3,4′-bpy)₂MoO₄]·3H₂O (1·3H₂O) in 80% yield. The structure of 1·3H₂O consists of a three-dimensional coordination polymer {Ni(3,4′-bpy)₂}_n²ⁿ⁺ with entrained {MoO₄}^2- tetrahedra and with water molecules of crystallization occupying channels within the bimetallic oxide-ligand framework. Crystal data: C₂₀H₁₆N₄O₄NiMo·3H ₂O (1·3H₂O), tetragonal P4₁2₁2, a=13.1866(5) Å, c=29.458(2) Å, V=5122.3(4) Å³, Z=8, D_calc=1.532 gcm^-3.

Original language	English (US)
Pages (from-to)	79-86
Number of pages	8
Journal	Inorganica Chimica Acta
Volume	332
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(02)00705-3
State	Published - Apr 17 2002

Keywords

Bimetallic oxide
Coordination polymer
Hybrid material
Nickel molybdate

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0020-1693(02)00705-3

Cite this

@article{91287b8508184245a8b625bf8c3b2924,

title = "A bimetallic oxide hybrid material constructed from a coordination complex polymer and molybdenum oxide subunits, [Ni(3,4′-bipyridine)2MoO4]·3H2O",

abstract = "The hydrothermal reaction of NiCl2·6H2O, MoO3, 3,4′-bipyridine (3,4′-bpy) and H2O in the mole ratio 1.0:1.0:2.1:1500 yields [Ni(3,4′-bpy)2MoO4]·3H2O (1·3H2O) in 80% yield. The structure of 1·3H2O consists of a three-dimensional coordination polymer {Ni(3,4′-bpy)2}n2n+ with entrained {MoO4}2- tetrahedra and with water molecules of crystallization occupying channels within the bimetallic oxide-ligand framework. Crystal data: C20H16N4O4NiMo·3H 2O (1·3H2O), tetragonal P41212, a=13.1866(5) {\AA}, c=29.458(2) {\AA}, V=5122.3(4) {\AA}3, Z=8, Dcalc=1.532 gcm-3.",

keywords = "Bimetallic oxide, Coordination polymer, Hybrid material, Nickel molybdate",

author = "LaDuca, {Robert L.} and Matthew Desiak and Rarig, {Randy S.} and Jon Zubieta",

note = "Funding Information: This work was supported by a grant from the National Science Foundation (CHE9987471). ",

year = "2002",

month = apr,

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doi = "10.1016/S0020-1693(02)00705-3",

language = "English (US)",

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TY - JOUR

T1 - A bimetallic oxide hybrid material constructed from a coordination complex polymer and molybdenum oxide subunits, [Ni(3,4′-bipyridine)2MoO4]·3H2O

AU - LaDuca, Robert L.

AU - Desiak, Matthew

AU - Rarig, Randy S.

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by a grant from the National Science Foundation (CHE9987471).

PY - 2002/4/17

Y1 - 2002/4/17

N2 - The hydrothermal reaction of NiCl2·6H2O, MoO3, 3,4′-bipyridine (3,4′-bpy) and H2O in the mole ratio 1.0:1.0:2.1:1500 yields [Ni(3,4′-bpy)2MoO4]·3H2O (1·3H2O) in 80% yield. The structure of 1·3H2O consists of a three-dimensional coordination polymer {Ni(3,4′-bpy)2}n2n+ with entrained {MoO4}2- tetrahedra and with water molecules of crystallization occupying channels within the bimetallic oxide-ligand framework. Crystal data: C20H16N4O4NiMo·3H 2O (1·3H2O), tetragonal P41212, a=13.1866(5) Å, c=29.458(2) Å, V=5122.3(4) Å3, Z=8, Dcalc=1.532 gcm-3.

AB - The hydrothermal reaction of NiCl2·6H2O, MoO3, 3,4′-bipyridine (3,4′-bpy) and H2O in the mole ratio 1.0:1.0:2.1:1500 yields [Ni(3,4′-bpy)2MoO4]·3H2O (1·3H2O) in 80% yield. The structure of 1·3H2O consists of a three-dimensional coordination polymer {Ni(3,4′-bpy)2}n2n+ with entrained {MoO4}2- tetrahedra and with water molecules of crystallization occupying channels within the bimetallic oxide-ligand framework. Crystal data: C20H16N4O4NiMo·3H 2O (1·3H2O), tetragonal P41212, a=13.1866(5) Å, c=29.458(2) Å, V=5122.3(4) Å3, Z=8, Dcalc=1.532 gcm-3.

KW - Bimetallic oxide

KW - Coordination polymer

KW - Hybrid material

KW - Nickel molybdate

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