A bimetallic oxide framework, [{Cu(bpy)}2Mo4O10(O3PCH2C6H4CH2PO3)2], constructed from novel {Mo4 O10 (O3 PR)4}n4 n - chains

Stephanie Jones; Hongxue Liu; Katherine Schmidtke; Charles C. O'Connor; Jon Zubieta

doi:10.1016/j.inoche.2009.12.008

A bimetallic oxide framework, [{Cu(bpy)}₂Mo₄O₁₀(O₃PCH₂C₆H₄CH₂PO₃)₂], constructed from novel {Mo₄ O₁₀ (O₃ PR)₄}_n^{4 n -} chains

Stephanie Jones, Hongxue Liu, Katherine Schmidtke, Charles C. O'Connor, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The hydrothermal reaction of Cu(CH₃CO₂)₂·H₂O, MoO₃, 2,2′-bipyridine (bpy), and p-xylene diphosphonic acid in the presence of HF provided blue crystals of the bimetallic oxide phase [{Cu(bpy)}₂Mo₄O₁₀(O₃PCH₂C₆H₄CH₂PO₃)₂] (1). The three-dimensional structure of 1 is constructed from {Mo₄ O₁₀ (O₃ PR)₄}_n^{4 n -} chains, decorated with {Cu(bpy)}²⁺ subunits and linked through the p-xylyl tether of the diphosphonate ligand. The molybdate building block within the chain is a tetranuclear {Mo₄O₁₀(O₃P)₈} cluster of edge- and corner-sharing {MoO₆} octahedra. Each phosphomolybdate chain is linked to four adjacent chains to generate the three-dimensional connectivity. Crystal data: C₁₈H₁₆CuMo₂N₂O₁₁P₂, fw = 753.69: monoclinic P2₁/c, a = 7.9719(8) Å, b = 14.0392(14) Å, c = 21.274(2) Å, β = 94.585(3)°, V = 2373.3(4) Å³, Z = 4, D_calc = 2.109 g cm^-3, R₁ = 0.0610.

Original language	English (US)
Pages (from-to)	298-301
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	13
Issue number	2
DOIs	https://doi.org/10.1016/j.inoche.2009.12.008
State	Published - Feb 2010

Keywords

Bimetallic oxide
Copper-molybdophosphonate material
Organic-inorganic hybrid material
X-ray structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.inoche.2009.12.008

Cite this

@article{6602abad85954f71aec8ab5e968e0e4c,

title = "A bimetallic oxide framework, [{Cu(bpy)}2Mo4O10(O3PCH2C6H4CH2PO3)2], constructed from novel {Mo4 O10 (O3 PR)4}n4 n - chains",

abstract = "The hydrothermal reaction of Cu(CH3CO2)2·H2O, MoO3, 2,2′-bipyridine (bpy), and p-xylene diphosphonic acid in the presence of HF provided blue crystals of the bimetallic oxide phase [{Cu(bpy)}2Mo4O10(O3PCH2C6H4CH2PO3)2] (1). The three-dimensional structure of 1 is constructed from {Mo4 O10 (O3 PR)4}n4 n - chains, decorated with {Cu(bpy)}2+ subunits and linked through the p-xylyl tether of the diphosphonate ligand. The molybdate building block within the chain is a tetranuclear {Mo4O10(O3P)8} cluster of edge- and corner-sharing {MoO6} octahedra. Each phosphomolybdate chain is linked to four adjacent chains to generate the three-dimensional connectivity. Crystal data: C18H16CuMo2N2O11P2, fw = 753.69: monoclinic P21/c, a = 7.9719(8) {\AA}, b = 14.0392(14) {\AA}, c = 21.274(2) {\AA}, β = 94.585(3)°, V = 2373.3(4) {\AA}3, Z = 4, Dcalc = 2.109 g cm-3, R1 = 0.0610.",

keywords = "Bimetallic oxide, Copper-molybdophosphonate material, Organic-inorganic hybrid material, X-ray structure",

author = "Stephanie Jones and Hongxue Liu and Katherine Schmidtke and O'Connor, {Charles C.} and Jon Zubieta",

note = "Funding Information: This work was supported by a Grant from the National Science Foundation ( CHE0907787 ). The magnetic studies were supported by a Grant from the Louisiana Board of Regents , through Contract No. LEQSF(2007-12)-ENH-PKSFI-PRS-04 . ",

year = "2010",

month = feb,

doi = "10.1016/j.inoche.2009.12.008",

language = "English (US)",

volume = "13",

pages = "298--301",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier",

number = "2",

}

TY - JOUR

T1 - A bimetallic oxide framework, [{Cu(bpy)}2Mo4O10(O3PCH2C6H4CH2PO3)2], constructed from novel {Mo4 O10 (O3 PR)4}n4 n - chains

AU - Jones, Stephanie

AU - Liu, Hongxue

AU - Schmidtke, Katherine

AU - O'Connor, Charles C.

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by a Grant from the National Science Foundation ( CHE0907787 ). The magnetic studies were supported by a Grant from the Louisiana Board of Regents , through Contract No. LEQSF(2007-12)-ENH-PKSFI-PRS-04 .

PY - 2010/2

Y1 - 2010/2

N2 - The hydrothermal reaction of Cu(CH3CO2)2·H2O, MoO3, 2,2′-bipyridine (bpy), and p-xylene diphosphonic acid in the presence of HF provided blue crystals of the bimetallic oxide phase [{Cu(bpy)}2Mo4O10(O3PCH2C6H4CH2PO3)2] (1). The three-dimensional structure of 1 is constructed from {Mo4 O10 (O3 PR)4}n4 n - chains, decorated with {Cu(bpy)}2+ subunits and linked through the p-xylyl tether of the diphosphonate ligand. The molybdate building block within the chain is a tetranuclear {Mo4O10(O3P)8} cluster of edge- and corner-sharing {MoO6} octahedra. Each phosphomolybdate chain is linked to four adjacent chains to generate the three-dimensional connectivity. Crystal data: C18H16CuMo2N2O11P2, fw = 753.69: monoclinic P21/c, a = 7.9719(8) Å, b = 14.0392(14) Å, c = 21.274(2) Å, β = 94.585(3)°, V = 2373.3(4) Å3, Z = 4, Dcalc = 2.109 g cm-3, R1 = 0.0610.

AB - The hydrothermal reaction of Cu(CH3CO2)2·H2O, MoO3, 2,2′-bipyridine (bpy), and p-xylene diphosphonic acid in the presence of HF provided blue crystals of the bimetallic oxide phase [{Cu(bpy)}2Mo4O10(O3PCH2C6H4CH2PO3)2] (1). The three-dimensional structure of 1 is constructed from {Mo4 O10 (O3 PR)4}n4 n - chains, decorated with {Cu(bpy)}2+ subunits and linked through the p-xylyl tether of the diphosphonate ligand. The molybdate building block within the chain is a tetranuclear {Mo4O10(O3P)8} cluster of edge- and corner-sharing {MoO6} octahedra. Each phosphomolybdate chain is linked to four adjacent chains to generate the three-dimensional connectivity. Crystal data: C18H16CuMo2N2O11P2, fw = 753.69: monoclinic P21/c, a = 7.9719(8) Å, b = 14.0392(14) Å, c = 21.274(2) Å, β = 94.585(3)°, V = 2373.3(4) Å3, Z = 4, Dcalc = 2.109 g cm-3, R1 = 0.0610.

KW - Bimetallic oxide

KW - Copper-molybdophosphonate material

KW - Organic-inorganic hybrid material

KW - X-ray structure

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U2 - 10.1016/j.inoche.2009.12.008

DO - 10.1016/j.inoche.2009.12.008

M3 - Article

AN - SCOPUS:74149084867

SN - 1387-7003

VL - 13

SP - 298

EP - 301

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 2

ER -