A bimetallic main group oxide cluster of the oxovanadium borate system: (H3NCH2CH2NH3)4[(VO) 12O4{B8O17(OH)4} 2{Mn(H2O)2}2] · H2O

Christopher J. Warren; Robert C. Haushalter; David J. Rose; Jon Zubieta

doi:10.1016/S0020-1693(98)00187-X

A bimetallic main group oxide cluster of the oxovanadium borate system: (H₃NCH₂CH₂NH₃)₄[(VO) ₁₂O₄{B₈O₁₇(OH)₄} ₂{Mn(H₂O)₂}₂] · H₂O

Christopher J. Warren, Robert C. Haushalter, David J. Rose, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

The hydrothermal reaction of (NH₄)₂B₄O₇, NaVO₃, ethylenediamine, MnC1₂ · 4H₂O and H₂O in the molar ratio 2.74:4:4:1:175 at 170°C for 5 days yields orange crystals of (H₃NCH₂CH₂NH₃)₄[(VO) ₁₂O₄{B₈O₁₇(OH)₄} ₂{Mn(H₂O)₂}₂] · H₂O (1·H₂O) in 75% yield. The structure consists of a continuous contorted V₁₂ ring, constructed from edge-sharing V(IV) square pyramids. Two {B₈O₁₇(OH)₄}_14- chains nestle in the cavities formed by the V₁₂ ring. The octahedral Mn(II) sites bridge two neighboring [(VO)₁₂O₄{B₈O₁₇(OH) ₄}₂]_12- clusters to produce a mixed metal boron oxide network with two-dimensional covalent connectivity. Crystal data: monoclinic C2/c, a= 13.4324(2), b=19.6998(1), c=24.0521(3) Å, β=98.820(1)°, Z=4, D_calc =2.282 g cm_-3; R=0.0462 for 7299 reflections.

Original language	English (US)
Pages (from-to)	123-129
Number of pages	7
Journal	Inorganica Chimica Acta
Volume	282
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(98)00187-X
State	Published - Nov 10 1998

Keywords

Borate complexes
Cluster complexes
Crystal structures
Oxovanadium complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0020-1693(98)00187-X

Cite this

@article{95d4b589380a4535b82903a7f3702708,

title = "A bimetallic main group oxide cluster of the oxovanadium borate system: (H3NCH2CH2NH3)4[(VO) 12O4{B8O17(OH)4} 2{Mn(H2O)2}2] · H2O",

abstract = "The hydrothermal reaction of (NH4)2B4O7, NaVO3, ethylenediamine, MnC12 · 4H2O and H2O in the molar ratio 2.74:4:4:1:175 at 170°C for 5 days yields orange crystals of (H3NCH2CH2NH3)4[(VO) 12O4{B8O17(OH)4} 2{Mn(H2O)2}2] · H2O (1·H2O) in 75% yield. The structure consists of a continuous contorted V12 ring, constructed from edge-sharing V(IV) square pyramids. Two {B8O17(OH)4}14- chains nestle in the cavities formed by the V12 ring. The octahedral Mn(II) sites bridge two neighboring [(VO)12O4{B8O17(OH) 4}2]12- clusters to produce a mixed metal boron oxide network with two-dimensional covalent connectivity. Crystal data: monoclinic C2/c, a= 13.4324(2), b=19.6998(1), c=24.0521(3) {\AA}, β=98.820(1)°, Z=4, Dcalc =2.282 g cm-3; R=0.0462 for 7299 reflections.",

keywords = "Borate complexes, Cluster complexes, Crystal structures, Oxovanadium complexes",

author = "Warren, {Christopher J.} and Haushalter, {Robert C.} and Rose, {David J.} and Jon Zubieta",

note = "Funding Information: The work at Syracuse University was supported by NSF Grant CHE9617232.",

year = "1998",

month = nov,

day = "10",

doi = "10.1016/S0020-1693(98)00187-X",

language = "English (US)",

volume = "282",

pages = "123--129",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

number = "1",

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TY - JOUR

T1 - A bimetallic main group oxide cluster of the oxovanadium borate system

T2 - (H3NCH2CH2NH3)4[(VO) 12O4{B8O17(OH)4} 2{Mn(H2O)2}2] · H2O

AU - Warren, Christopher J.

AU - Haushalter, Robert C.

AU - Rose, David J.

AU - Zubieta, Jon

N1 - Funding Information: The work at Syracuse University was supported by NSF Grant CHE9617232.

PY - 1998/11/10

Y1 - 1998/11/10

N2 - The hydrothermal reaction of (NH4)2B4O7, NaVO3, ethylenediamine, MnC12 · 4H2O and H2O in the molar ratio 2.74:4:4:1:175 at 170°C for 5 days yields orange crystals of (H3NCH2CH2NH3)4[(VO) 12O4{B8O17(OH)4} 2{Mn(H2O)2}2] · H2O (1·H2O) in 75% yield. The structure consists of a continuous contorted V12 ring, constructed from edge-sharing V(IV) square pyramids. Two {B8O17(OH)4}14- chains nestle in the cavities formed by the V12 ring. The octahedral Mn(II) sites bridge two neighboring [(VO)12O4{B8O17(OH) 4}2]12- clusters to produce a mixed metal boron oxide network with two-dimensional covalent connectivity. Crystal data: monoclinic C2/c, a= 13.4324(2), b=19.6998(1), c=24.0521(3) Å, β=98.820(1)°, Z=4, Dcalc =2.282 g cm-3; R=0.0462 for 7299 reflections.

AB - The hydrothermal reaction of (NH4)2B4O7, NaVO3, ethylenediamine, MnC12 · 4H2O and H2O in the molar ratio 2.74:4:4:1:175 at 170°C for 5 days yields orange crystals of (H3NCH2CH2NH3)4[(VO) 12O4{B8O17(OH)4} 2{Mn(H2O)2}2] · H2O (1·H2O) in 75% yield. The structure consists of a continuous contorted V12 ring, constructed from edge-sharing V(IV) square pyramids. Two {B8O17(OH)4}14- chains nestle in the cavities formed by the V12 ring. The octahedral Mn(II) sites bridge two neighboring [(VO)12O4{B8O17(OH) 4}2]12- clusters to produce a mixed metal boron oxide network with two-dimensional covalent connectivity. Crystal data: monoclinic C2/c, a= 13.4324(2), b=19.6998(1), c=24.0521(3) Å, β=98.820(1)°, Z=4, Dcalc =2.282 g cm-3; R=0.0462 for 7299 reflections.

KW - Borate complexes

KW - Cluster complexes

KW - Crystal structures

KW - Oxovanadium complexes

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EP - 129

JO - Inorganica Chimica Acta

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