TY - JOUR
T1 - 3‐ and 3,6‐Silylated 2‐Pyridinethiols
T2 - New Hindered Bidentate Ligands and Their Novel Silver and Copper Clusters
AU - Block, Eric
AU - Gernon, Michael
AU - Kang, Hyunkyu
AU - Zubieta, Jon
PY - 1988/10
Y1 - 1988/10
N2 - Analogous hexanuclear, paddlewheel complexes are formed by reaction of AgI and CuI precursors with the new ligand 3‐tri‐methylsilyl‐2‐pyridinethiol. MS2N coordination has thus been achieved for the first time (see right, • = metal). The large Me3Si group of the ligand prevents polymerization, which is observed for complexes of the parent compound. The ligand is accessible by silylation of 2‐pyridinethiol. (Figure Presented.)
AB - Analogous hexanuclear, paddlewheel complexes are formed by reaction of AgI and CuI precursors with the new ligand 3‐tri‐methylsilyl‐2‐pyridinethiol. MS2N coordination has thus been achieved for the first time (see right, • = metal). The large Me3Si group of the ligand prevents polymerization, which is observed for complexes of the parent compound. The ligand is accessible by silylation of 2‐pyridinethiol. (Figure Presented.)
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U2 - 10.1002/anie.198813421
DO - 10.1002/anie.198813421
M3 - Article
AN - SCOPUS:84985534834
SN - 0570-0833
VL - 27
SP - 1342
EP - 1344
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 10
ER -