π-Arene complexes. II. Synthesis, characterization and reactivity towards arene and thioether substitution of π-arenedicarbonyl(thioether)chromium(0)complexes. Crystal structure of cis-tetracarbonyl(methyl-1,3-dithian-2-methyl-2-dithiocarboxylate)chromium(0)

Simon Lotz; Minet Schindehutte; Marthie M. van Dyk; Jan L.M. Dillen; Petrus H. van Rooyen

doi:10.1016/0022-328X(85)88072-4

π-Arene complexes. II. Synthesis, characterization and reactivity towards arene and thioether substitution of π-arenedicarbonyl(thioether)chromium(0)complexes. Crystal structure of cis-tetracarbonyl(methyl-1,3-dithian-2-methyl-2-dithiocarboxylate)chromium(0)

Simon Lotz, Minet Schindehutte, Marthie M. van Dyk, Jan L.M. Dillen, Petrus H. van Rooyen

Research output: Contribution to journal › Article › peer-review

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Abstract

A carbonyl ligand of π-arenetricarbonylchromiun(0) complexes is photochemically displaced to give π-arenedicarbonyl complexes of chromium(0) with thio-ether ligands. In contrast, irradiation of π-arenetricarbonylchromium compounds with dithio-ester and trithiocarbonate ligands yields only pentacarbonyl complexes. Substitution of the π-arene ring, the thio-ether ligand, or both, is easily achieved at room temperature and in polar solvents. The crystal structure of cis-tetracarbonyl(methyl-1,3-dithian-2-methyl-2-dithiocarboxylate)chromium(0) shows remarkably similar CrS bond distances of 2.379(2) and 2.383(2) Å for the respective thio-ether and dithio-ester sulphur-donor atoms of the bidentate ligand.

Original language	English (US)
Pages (from-to)	51-61
Number of pages	11
Journal	Journal of Organometallic Chemistry
Volume	295
Issue number	1
DOIs	https://doi.org/10.1016/0022-328X(85)88072-4
State	Published - Nov 5 1985
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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Lotz, S., Schindehutte, M., van Dyk, M. M., Dillen, J. L. M., & van Rooyen, P. H. (1985). π-Arene complexes. II. Synthesis, characterization and reactivity towards arene and thioether substitution of π-arenedicarbonyl(thioether)chromium(0)complexes. Crystal structure of cis-tetracarbonyl(methyl-1,3-dithian-2-methyl-2-dithiocarboxylate)chromium(0). Journal of Organometallic Chemistry, 295(1), 51-61. https://doi.org/10.1016/0022-328X(85)88072-4

π-Arene complexes. II. Synthesis, characterization and reactivity towards arene and thioether substitution of π-arenedicarbonyl(thioether)chromium(0)complexes. Crystal structure of cis-tetracarbonyl(methyl-1,3-dithian-2-methyl-2-dithiocarboxylate)chromium(0). / Lotz, Simon; Schindehutte, Minet; van Dyk, Marthie M. et al.
In: Journal of Organometallic Chemistry, Vol. 295, No. 1, 05.11.1985, p. 51-61.

Research output: Contribution to journal › Article › peer-review

Lotz, S, Schindehutte, M, van Dyk, MM, Dillen, JLM & van Rooyen, PH 1985, 'π-Arene complexes. II. Synthesis, characterization and reactivity towards arene and thioether substitution of π-arenedicarbonyl(thioether)chromium(0)complexes. Crystal structure of cis-tetracarbonyl(methyl-1,3-dithian-2-methyl-2-dithiocarboxylate)chromium(0)', Journal of Organometallic Chemistry, vol. 295, no. 1, pp. 51-61. https://doi.org/10.1016/0022-328X(85)88072-4

Lotz S, Schindehutte M, van Dyk MM, Dillen JLM, van Rooyen PH. π-Arene complexes. II. Synthesis, characterization and reactivity towards arene and thioether substitution of π-arenedicarbonyl(thioether)chromium(0)complexes. Crystal structure of cis-tetracarbonyl(methyl-1,3-dithian-2-methyl-2-dithiocarboxylate)chromium(0). Journal of Organometallic Chemistry. 1985 Nov 5;295(1):51-61. doi: 10.1016/0022-328X(85)88072-4

Lotz, Simon ; Schindehutte, Minet ; van Dyk, Marthie M. et al. / π-Arene complexes. II. Synthesis, characterization and reactivity towards arene and thioether substitution of π-arenedicarbonyl(thioether)chromium(0)complexes. Crystal structure of cis-tetracarbonyl(methyl-1,3-dithian-2-methyl-2-dithiocarboxylate)chromium(0). In: Journal of Organometallic Chemistry. 1985 ; Vol. 295, No. 1. pp. 51-61.

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abstract = "A carbonyl ligand of π-arenetricarbonylchromiun(0) complexes is photochemically displaced to give π-arenedicarbonyl complexes of chromium(0) with thio-ether ligands. In contrast, irradiation of π-arenetricarbonylchromium compounds with dithio-ester and trithiocarbonate ligands yields only pentacarbonyl complexes. Substitution of the π-arene ring, the thio-ether ligand, or both, is easily achieved at room temperature and in polar solvents. The crystal structure of cis-tetracarbonyl(methyl-1,3-dithian-2-methyl-2-dithiocarboxylate)chromium(0) shows remarkably similar CrS bond distances of 2.379(2) and 2.383(2) {\AA} for the respective thio-ether and dithio-ester sulphur-donor atoms of the bidentate ligand.",

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AU - Lotz, Simon

AU - Schindehutte, Minet

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N2 - A carbonyl ligand of π-arenetricarbonylchromiun(0) complexes is photochemically displaced to give π-arenedicarbonyl complexes of chromium(0) with thio-ether ligands. In contrast, irradiation of π-arenetricarbonylchromium compounds with dithio-ester and trithiocarbonate ligands yields only pentacarbonyl complexes. Substitution of the π-arene ring, the thio-ether ligand, or both, is easily achieved at room temperature and in polar solvents. The crystal structure of cis-tetracarbonyl(methyl-1,3-dithian-2-methyl-2-dithiocarboxylate)chromium(0) shows remarkably similar CrS bond distances of 2.379(2) and 2.383(2) Å for the respective thio-ether and dithio-ester sulphur-donor atoms of the bidentate ligand.

AB - A carbonyl ligand of π-arenetricarbonylchromiun(0) complexes is photochemically displaced to give π-arenedicarbonyl complexes of chromium(0) with thio-ether ligands. In contrast, irradiation of π-arenetricarbonylchromium compounds with dithio-ester and trithiocarbonate ligands yields only pentacarbonyl complexes. Substitution of the π-arene ring, the thio-ether ligand, or both, is easily achieved at room temperature and in polar solvents. The crystal structure of cis-tetracarbonyl(methyl-1,3-dithian-2-methyl-2-dithiocarboxylate)chromium(0) shows remarkably similar CrS bond distances of 2.379(2) and 2.383(2) Å for the respective thio-ether and dithio-ester sulphur-donor atoms of the bidentate ligand.

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π-Arene complexes. II. Synthesis, characterization and reactivity towards arene and thioether substitution of π-arenedicarbonyl(thioether)chromium(0)complexes. Crystal structure of cis-tetracarbonyl(methyl-1,3-dithian-2-methyl-2-dithiocarboxylate)chromium(0)

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