[μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)-butane-1,4-diamine] bis[dinitratocadmium(II)]

Mark Bartholomä; Hoi Cheung; Jon Zubieta

doi:10.1107/S1600536810034549

[μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)-butane-1,4-diamine] bis[dinitratocadmium(II)]

Mark Bartholomä, Hoi Cheung, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The title dinuclear cadmium complex, [Cd₂(NO₃) ₄(C₂₈H₃₂N₆)], is located on an inversion center. The unique Cd^II ion displays a 5 + 2 coordination. A distorted square-pyramidal geometry is formed by the dipicolyl-amine group of the ligand via the N atoms in a meridional fashion and two O atoms of the nitrate ligands with short Cd - O distances. The coordination is completed by two loosely bound O atoms of the nitrate ligands.

Original language	English (US)
Pages (from-to)	m1197
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	10
DOIs	https://doi.org/10.1107/S1600536810034549
State	Published - Oct 2010

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1107/S1600536810034549

Cite this

@article{969f9c8716d74a50a099ab31705bbba3,

title = "[μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)-butane-1,4-diamine] bis[dinitratocadmium(II)]",

abstract = "The title dinuclear cadmium complex, [Cd2(NO3) 4(C28H32N6)], is located on an inversion center. The unique CdII ion displays a 5 + 2 coordination. A distorted square-pyramidal geometry is formed by the dipicolyl-amine group of the ligand via the N atoms in a meridional fashion and two O atoms of the nitrate ligands with short Cd - O distances. The coordination is completed by two loosely bound O atoms of the nitrate ligands.",

author = "Mark Bartholom{\"a} and Hoi Cheung and Jon Zubieta",

year = "2010",

month = oct,

doi = "10.1107/S1600536810034549",

language = "English (US)",

volume = "66",

pages = "m1197",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "10",

}

TY - JOUR

T1 - [μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)-butane-1,4-diamine] bis[dinitratocadmium(II)]

AU - Bartholomä, Mark

AU - Cheung, Hoi

AU - Zubieta, Jon

PY - 2010/10

Y1 - 2010/10

N2 - The title dinuclear cadmium complex, [Cd2(NO3) 4(C28H32N6)], is located on an inversion center. The unique CdII ion displays a 5 + 2 coordination. A distorted square-pyramidal geometry is formed by the dipicolyl-amine group of the ligand via the N atoms in a meridional fashion and two O atoms of the nitrate ligands with short Cd - O distances. The coordination is completed by two loosely bound O atoms of the nitrate ligands.

AB - The title dinuclear cadmium complex, [Cd2(NO3) 4(C28H32N6)], is located on an inversion center. The unique CdII ion displays a 5 + 2 coordination. A distorted square-pyramidal geometry is formed by the dipicolyl-amine group of the ligand via the N atoms in a meridional fashion and two O atoms of the nitrate ligands with short Cd - O distances. The coordination is completed by two loosely bound O atoms of the nitrate ligands.

UR - http://www.scopus.com/inward/record.url?scp=77957827385&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77957827385&partnerID=8YFLogxK

U2 - 10.1107/S1600536810034549

DO - 10.1107/S1600536810034549

M3 - Article

C2 - 21587358

AN - SCOPUS:77957827385

SN - 1600-5368

VL - 66

SP - m1197

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 10

ER -

[μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)-butane-1,4-diamine] bis[dinitratocadmium(II)]

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this