TY - JOUR
T1 - [μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)-butane-1,4-diamine] bis[dibromidocopper(II)]
AU - Bartholomä, Mark
AU - Cheung, Hoi
AU - Zubieta, Jon
PY - 2010/10
Y1 - 2010/10
N2 - The title dinuclear copper complex, [Cu2Br4(C 28H32N6)], is located on an inversion center. The unique CuII ion is in a slightly distorted square-pyramidal environment in which the N atoms of a dipicolyl-amine group and a bromide ligand form the basal plane. The apical site is occupied by a second Br atom. While the Cu - N distances involving the pyridine N atoms are the same within experimental error, the Cu - N distance involving the tertiary N atom is slightly elongated. Due to the typical Jahn-Teller distortion of copper(II) complexes, the apical Cu - Br distance is elongated.
AB - The title dinuclear copper complex, [Cu2Br4(C 28H32N6)], is located on an inversion center. The unique CuII ion is in a slightly distorted square-pyramidal environment in which the N atoms of a dipicolyl-amine group and a bromide ligand form the basal plane. The apical site is occupied by a second Br atom. While the Cu - N distances involving the pyridine N atoms are the same within experimental error, the Cu - N distance involving the tertiary N atom is slightly elongated. Due to the typical Jahn-Teller distortion of copper(II) complexes, the apical Cu - Br distance is elongated.
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U2 - 10.1107/S1600536810034537
DO - 10.1107/S1600536810034537
M3 - Article
C2 - 21587359
AN - SCOPUS:77957848066
SN - 1600-5368
VL - 66
SP - m1198
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 10
ER -