Karin Ruhlandt – Research Output

2017

A Modern Twist to a Classic Synthetic Route: Ph₃Bi-Based Redox Transmetalation Protolysis (RTP) for the Preparation of Barium Metalorganic Species

Takahashi, Y., O'Brien, A., Deacon, G. B., Andrews, P. C., Wolf, M., Torvisco, A., Gillett-Kunnath, M. M. & Ruhlandt-Senge, K. Oct 2 2017 In : Inorganic Chemistry. 56, 19, p. 11480-11489 10 p.

Research output: Contribution to journal › Article

Barium

barium

Metals

routes

Amides

2016

2 Citations

Functionalization of boron nitride nanosheets (BNNSs) by organic polymers: formation of substituted polythiophene–BNNS structures

Petrelli, C., Goos, A., Ruhlandt-Senge, K. & Spencer, J. T. May 1 2016 In : Journal of Materials Science. 51, 10, p. 4952-4962 11 p.

Research output: Contribution to journal › Article

Organic polymers

Boron nitride

Nanosheets

Thiophenes

Thiophene

5 Citations

Metal-organodiphosphonate chemistry: Hydrothermal syntheses and structures of Ca(II) coordination polymers with xylyldiphosphonate ligands

Lopez-Diaz, V., Smith Pellizerri, T. M., Lijewski, M. D., Ruhlandt, K. & Zubieta, J. Feb 24 2016 In : Inorganica Chimica Acta. 441, p. 109-116 8 p.

Research output: Contribution to journal › Article

Organophosphonates

Hydrothermal synthesis

Diphosphonates

coordination polymers

Hydrogen bonds

2013

10 Citations

Heavy alkaline-earth metal organometallic and metal organic chemistry: Synthetic methods and properties

Torvisco, A. & Ruhlandt-Senge, K. 2013 In : Topics in Organometallic Chemistry. 45, p. 1-28 28 p.

Research output: Contribution to journal › Article

Alkaline Earth Metals

Alkaline earth metals

Organometallics

Heavy metals

Metals

12 Citations

M-F interactions and heterobimetallics: Furthering the understanding of heterobimetallic stabilization

Buchanan, W. D. & Ruhlandt-Senge, K. Aug 5 2013 In : Chemistry - A European Journal. 19, 32, p. 10708-10715 8 p.

Research output: Contribution to journal › Article

Stabilization

Ligands

Metals

Europium

Organic Chemicals

2012

7 Citations

Alkaline earth metal di- and triphenylmethanides: Analysis of ion association modes

Guino-O, M. A., Torvisco, A., Teng, W. & Ruhlandt-Senge, K. Jul 1 2012 In : Inorganica Chimica Acta. 389, p. 122-130 9 p.

Research output: Contribution to journal › Article

Alkaline Earth Metals

Alkaline earth metals

alkaline earth metals

Hempa

Metals

2011

64 Citations

Advances in alkaline earth-nitrogen chemistry

Torvisco, A., O'Brien, A. Y. & Ruhlandt-Senge, K. Jun 2011 In : Coordination Chemistry Reviews. 255, 11-12, p. 1268-1292 25 p.

Research output: Contribution to journal › Article

Alkaline Earth Metals

Nitrogen

Earth (planet)

Catalysis

Metals

Electronic coupling in diiron complexes with the butadienediyl-bridged chain

Sponsler, M. B., Englich, U., Ruhlandt, K., Jung, S. C., Ahn, H. G. & Chung, M. C. Feb 2011 In : Journal of Nanoscience and Nanotechnology. 11, 2, p. 1534-1537 4 p.

Research output: Contribution to journal › Article

X ray crystallography

Carbon Monoxide

Cyclic voltammetry

Nuclear magnetic resonance

methylidyne

9 Citations

Ligand and coligand effects on ion association in magnesium amides

Torvisco, A. & Ruhlandt-Senge, K. Mar 14 2011 In : Organometallics. 30, 5, p. 986-991 6 p.

Research output: Contribution to journal › Article

Hempa

Amides

Magnesium

amides

magnesium

27 Citations

S-Block organometallics: Analysis of ion-association and noncovalent interactions on structure and function in benzyl-based compounds

Torvisco, A. & Ruhlandt-Senge, K. Dec 19 2011 In : Inorganic Chemistry. 50, 24, p. 12223-12240 18 p.

Research output: Contribution to journal › Article

Organometallics

Metals

Alkaline Earth Metals

Association reactions

Ions

7 Citations

Synthesis, characterization, and crystal structure of the 3-D metal organic framework {[Ba(in)(H2O)6][in]}∞

Rosado, P. J. & Ruhlandt-Senge, K. Jan 10 2011 In : Journal of Coordination Chemistry. 64, 1, p. 186-193 8 p.

Research output: Contribution to journal › Article

Crystal structure

Metals

crystal structure

Anions

Negative ions

3 Citations

Synthesis and characterization of cyano-substituted carborane-based compounds. Molecular structure of [1-(4-C 7H 7)-12-(C 5H 3-3-(CN)-3,4-(CH 3) 2)-C 2B 10H 10]

Taylor, J., Vargas, W., Torvisco, A., Ruhlandt-Senge, K. & Spencer, J. T. Oct 28 2011 In : Dalton Transactions. 40, 40, p. 10585-10591 7 p.

Research output: Contribution to journal › Article

Molecular structure

Nuclear magnetic resonance

Substitution reactions

Single crystals

X rays

2010

26 Citations

Highly volatile alkaline earth metal fluoroalkoxides

Buchanan, W. D., Guino-O, M. A. & Ruhlandt-Senge, K. Aug 2 2010 In : Inorganic Chemistry. 49, 15, p. 7144-7155 12 p.

Research output: Contribution to journal › Article

Alkaline Earth Metals

alkaline earth metals

tetrahydrofuran

sublimation

alkanes

57 Citations

Synthesis and stabilization - Advances in organoalkaline earth metal chemistry

Buchanan, W. D., Allis, D. G. & Ruhlandt-Senge, K. Jul 7 2010 In : Chemical Communications. 46, 25, p. 4449-4465 17 p.

Research output: Contribution to journal › Article

Stabilization

Metals

Earth (planet)

Alkaline Earth Metals

Alkaline earth metals

2009

34 Citations

Charge-separated and molecular heterobimetallic rare earth-rare earth and alkaline earth-rare earth aryloxo complexes featuring intramolecular metal-π-arene interactions

Deacon, G. B., Junk, P. C., Moxey, G. J., Ruhlandt-Senge, K., Prix, C. S. & Zuniga, M. F. May 25 2009 In : Chemistry - A European Journal. 15, 22, p. 5503-5519 17 p.

Research output: Contribution to journal › Article

Alkaline Earth Metals

Rare earths

Metals

Rare Earth Metals

Toluene

27 Citations

Heavy alkali metal amides: Role of secondary interactions in metal stabilization

Torvisco, A., Decker, K., Uhlig, F. & Ruhlandt-Senge, K. 2009 In : Inorganic Chemistry. 48, 23, p. 11459-11465 7 p.

Research output: Contribution to journal › Article

Alkali Metals

heavy metals

Amides

alkali metals

amides

14 Citations

Ion association trends in alkaline earth-metal tetraphenylborates

Verma, A., Guino-O, M., Gillett-Kunnath, M., Teng, W. & Ruhlandt-Senge, K. May 2009 In : Zeitschrift fur Anorganische und Allgemeine Chemie. 635, 6-7, p. 903-913 11 p.

Research output: Contribution to journal › Article

Tetraphenylborate

Alkaline Earth Metals

Association reactions

Ions

Coordination Complexes

18 Citations

Metal based synthetic routes to heavy alkaline earth aryloxo complexes involving ligands of moderate steric bulk

Deacon, G. B., Junk, P. C., Moxey, G. J., Guino-O, M. & Ruhlandt-Senge, K. Jun 16 2009 In : Journal of the Chemical Society. Dalton Transactions. 25, p. 4878-4887 10 p.

Research output: Contribution to journal › Article

Metals

Earth (planet)

Ligands

Atoms

Alkaline Earth Metals

21 Citations

When VSEPR fails: Experimental and theoretical investigations of the behavior of alkaline-earth-metal acetylides

Guino-O, M. A., Alexander, J. S., McKee, M. L., Hope, H., Englich, U. B. & Ruhlandt-Senge, K. 2009 In : Chemistry - A European Journal. 15, 44, p. 11842-11852 11 p.

Research output: Contribution to journal › Article

Alkaline Earth Metals

Heavy metals

Derivatives

Geometry

Communication

10 Citations

π-Coordination as a structure determining principle: Structural characterization of [K(Odpp)]∞, and {[K2(Odpp)2H2O]2}∞

Buchanan, W. D., Nagle, E. D. & Ruhlandt-Senge, K. Dec 2009 In : Main Group Chemistry. 8, 4, p. 263-273 11 p.

Research output: Contribution to journal › Article

Polymers

Ladders

Potassium

Display devices

2008

30 Citations

A unique heterobimetallic benzyl calciate - An organometallic mixed-metal species involving a heavy alkaline-earth metal

Guino-O, M. A., Campana, C. F. & Ruhlandt-Senge, K. 2008 In : Chemical Communications. 14, p. 1692-1694 3 p.

Research output: Contribution to journal › Article

Alkaline Earth Metals

Alkaline earth metals

Organometallics

Complexation

Heavy metals

24 Citations

BiPh3 - A convenient synthon for heavy alkaline-earth metal amides

Gillett-Kunnath, M. M., MacLellan, J. G., Forsyth, C. M., Andrews, P. C., Deacon, G. B. & Ruhlandt-Senge, K. 2008 In : Chemical Communications. 37, p. 4490-4492 3 p.

Research output: Contribution to journal › Article

Alkaline Earth Metals

Alkaline earth metals

Amides

Heavy metals

30 Citations

Developments in heterobimetallic s-block systems: Synthesis and structural survey of molecular M/Ae (M = Li, Na, K, Cs; Ae = Ca, Sr) aryloxo complexes

Zuniga, M. F., Deacon, G. B. & Ruhlandt-Senge, K. Jun 2 2008 In : Inorganic Chemistry. 47, 11, p. 4669-4681 13 p.

Research output: Contribution to journal › Article

Strontium

tetrahydrofuran

strontium

calcium

Lewis Bases

16 Citations

More than steric effects: Unlocking the coordination chemistry of barium pyrazolates

O'Brien, A. Y., Hitzbleck, J., Torvisco, A., Deacon, G. B. & Ruhlandt-Senge, K. 2008 In : European Journal of Inorganic Chemistry. 1, p. 172-182 11 p.

Research output: Contribution to journal › Article

Barium

Bearings (structural)

Alkaline Earth Metals

Coordination Complexes

Heavy Metals

23 Citations

Porphyrin complexes containing coordinated BOB groups: Synthesis, chemical reactivity and the structure of [BOB(tpClpp)]2+

Belcher, W. J., Hodgson, M. C., Sumida, K., Torvisco, A., Ruhlandt-Senge, K., Ware, D. C., Boyd, P. D. W. & Brothers, P. J. 2008 In : Dalton Transactions. 12, p. 1602-1614 13 p.

Research output: Contribution to journal › Article

Chemical reactivity

Boron

Porphyrins

Discrete Fourier transforms

Hydrolysis

7 Citations

The metal influence on the structural chemistry of alkynes: Synthetic, spectroscopic and structural studies on magnesium acetylides

Guino-O, M. A., Baker, E. & Ruhlandt-Senge, K. 2008 In : Journal of Coordination Chemistry. 61, 1, p. 125-136 12 p.

Research output: Contribution to journal › Article

Alkynes

alkynes

Magnesium

magnesium

Metals

12 Citations

The supramolecular architecture of arene complexes of bis(polyfluorophenyl) -mercurials

Deacon, G. B., Forsyth, C. M., Junk, P. C., Ness, T. J., Izgorodina, E., Baldamus, J., Meyer, G., Pantenburg, I., Hitzbleck, J. & Ruhlandt-Senge, K. Oct 2008 In : European Journal of Inorganic Chemistry. 30, p. 4770-4780 11 p.

Research output: Contribution to journal › Article

Mercury

Hexanes

Brick

Crystal structure

Crystalline materials

2007

7 Citations

Alkali metal diphenylmethanides: Synthetic, computational and structural studies

Alexander, J. S., Allis, D. G., Teng, W. & Ruhlandt-Senge, K. 2007 In : Chemistry - A European Journal. 13, 35, p. 9899-9911 13 p.

Research output: Contribution to journal › Article

Alkali Metals

Metals

Organometallic Compounds

Anions

Electrostatics

18 Citations

Lithium aryloxo magnesiates: An examination of ligand size and donor effects

Zuniga, M. F., Kreutzer, J., Teng, W. & Ruhlandt-Senge, K. Nov 26 2007 In : Inorganic Chemistry. 46, 24, p. 10400-10409 10 p.

Research output: Contribution to journal › Article

Lithium

Butylated Hydroxytoluene

lithium

examination

Ligands

29 Citations

New structural features in heavy alkaline earth-metal chemistry molecular heterobimetallic group 1, Ba complexes

Zuniga, M. F., Deacon, G. B. & Ruhlandt-Senge, K. 2007 In : Chemistry - A European Journal. 13, 7, p. 1921-1928 8 p.

Research output: Contribution to journal › Article

Alkaline Earth Metals

Heavy metals

Lewis Bases

Alkalies

Ether

29 Citations

Structural trends in alkaline earth and rare earth metal 3,5-diisopropylpyrazolates

Hitzbleck, J., Deacon, G. B. & Ruhlandt-Senge, K. 2007 In : European Journal of Inorganic Chemistry. 4, p. 592-601 10 p.

Research output: Contribution to journal › Article

Rare Earth Metals

Earth (planet)

Ligands

Toluene

Magnesium

3 Citations

Synthetic, structural, and theoretical investigations of alkali metal germanium hydrides - Contact molecules and separated ions

Teng, W., Allis, D. G. & Ruhlandt-Senge, K. 2007 In : Chemistry - A European Journal. 13, 4, p. 1309-1319 11 p.

Research output: Contribution to journal › Article

Germanium

Alkali Metals

Crown Ethers

Hydrides

Ions

25 Citations

Temperature-dependent coordination of phosphine to five-coordinate alkenylruthenium complexes

Seetharaman, S. K., Chung, M. C., Englich, U., Ruhlandt-Senge, K. & Sponsler, M. B. Jan 22 2007 In : Inorganic Chemistry. 46, 2, p. 561-567 7 p.

Research output: Contribution to journal › Article

phosphine

Carbon Monoxide

phosphines

methylidyne

Temperature

2006

25 Citations

From monomers to solids: Controlled hydrolysis to form novel, heteroleptic hydroxide-containing complexes

Teng, W., Guino-o, M., Hitzbleck, J., Englich, U. & Ruhlandt-Senge, K. Nov 13 2006 In : Inorganic Chemistry. 45, 23, p. 9531-9539 9 p.

Research output: Contribution to journal › Article

Alkaline Earth Metals

hydroxides

hydrolysis

Hydrolysis

Strontium

29 Citations

Role of donor and secondary interactions in the structures and thermal properties of alkaline-earth and rare-earth metal pyrazolates

Hitzbleck, J., O'Brien, A. Y., Deacon, G. B. & Ruhlandt-Senge, K. Dec 11 2006 In : Inorganic Chemistry. 45, 25, p. 10329-10337 9 p.

Research output: Contribution to journal › Article

Rare Earth Metals

tetrahydrofuran

rare earth elements

Thermodynamic properties

thermodynamic properties

2005

12 Citations

Influence of the steric demand of the 2,4,6-trialkylphenyl substituents on the structures and reactivity of diarylzinc

Westerhausen, M., Oßberger, M. W., Alexander, J. S. & Ruhlandt-Senge, K. 2005 In : Zeitschrift fur Anorganische und Allgemeine Chemie. 631, 13-14, p. 2836-2841 6 p.

Research output: Contribution to journal › Article

Cesium

Molecules

Cations

Zinc

Toluene

9 Citations

Pyridine-ring alkylation of cytotoxic r-1,c-3,c-5-tris[(2-pyridylmethyl)- amino]cyclohexane chelators: Structural and electronic properties of the Mn II, FeII, NiII, CuII and Zn II complexes

Childers, M. L., Su, F., Przyborowska, A. M., Bishwokarma, B., Park, G., Brechbiel, M. W., Torti, S. V., Torti, F. M., Broker, G., Alexander, J. S., Rogers, R. D., Ruhlandt-Senge, K. & Planalp, R. P. Oct 7 2005 In : European Journal of Inorganic Chemistry. 19, p. 3971-3982 12 p.

Research output: Contribution to journal › Article

Alkylation

Chelating Agents

Electronic properties

Structural properties

Cytotoxicity

10 Citations

Syntheses and structures of the first heavy-alkali-metal tris(trimethylsilyl)germanides

Teng, W. & Ruhlandt-Senge, K. Apr 8 2005 In : Chemistry - A European Journal. 11, 8, p. 2462-2470 9 p.

Research output: Contribution to journal › Article

Alkali Metals

Heavy metals

Ions

Crown Ethers

X ray crystallography

46 Citations

Synthesis and structures of monomeric magnesium, calcium, strontium, and barium amides involving the N,N-(2,4,6-trimethylphenyl)(trimethylsilyl)amido ligand

Gillett-Kunnath, M., Teng, W., Vargas, W. & Ruhlandt-Senge, K. Jun 27 2005 In : Inorganic Chemistry. 44, 13, p. 4862-4870 9 p.

Research output: Contribution to journal › Article

Strontium

Barium

Amides

strontium

Magnesium

2004

54 Citations

Heavy alkaline earth metal pyrazolates: Synthetic pathways, structural trends, and comparison with divalent lanthanoids

Hitzbleck, J., O'Brien, A. Y., Forsyth, C. M., Deacon, G. B. & Ruhlandt-Senge, K. Jul 5 2004 In : Chemistry - A European Journal. 10, 13, p. 3315-3323 9 p.

Research output: Contribution to journal › Article

Alkaline Earth Metals

Lanthanoid Series Elements

Heavy metals

Ligands

Metals

50 Citations

Linear finite "mers" - Homoleptic polynuclear heavy alkaline earth metal pyrazolates

Hitzbleck, J., Deacon, G. B. & Ruhlandt-Senge, K. Oct 4 2004 In : Angewandte Chemie (International Edition in English). 43, 39, p. 5218-5220 3 p.

Research output: Contribution to journal › Article

Alkaline Earth Metals

Alkaline earth metals

Heavy metals

Metals

Strontium

41 Citations

More Arrows in the Quiver: New Pathways and Old Problems with Heavy Alkaline Earth Metal Diphenylmethanides

Alexander, J. S. & Ruhlandt-Senge, K. Mar 5 2004 In : Chemistry - A European Journal. 10, 5, p. 1274-1280 7 p.

Research output: Contribution to journal › Article

Alkaline Earth Metals

Organometallics

Heavy metals

Earth (planet)

Barium

31 Citations

Syntheses and structures of the first heavy alkaline earth metal bis(tris(trimethylsilyl))silanides

Teng, W. & Ruhlandt-Senge, K. May 24 2004 In : Organometallics. 23, 11, p. 2694-2700 7 p.

Research output: Contribution to journal › Article

Alkaline Earth Metals

alkaline earth metals

heavy metals

Hempa

Heavy metals

23 Citations

Syntheses and structures of the first heavy alkaline earth metal germanides M(THF)n(Ge(SiMe3)3)2 (M = Ca, n = 3; M = Sr, n = 3; and M = Ba, n = 4)

Teng, W. & Ruhlandt-Senge, K. Mar 1 2004 In : Organometallics. 23, 5, p. 952-956 5 p.

Research output: Contribution to journal › Article

Barium Compounds

Strontium compounds

strontium compounds

barium compounds

calcium compounds

10 Citations

Synthesis and reactivity of novel alkali metal stannides

Schollmeier, T., Englich, U., Fischer, R., Prass, I., Ruhlandt, K., Schürmann, M. & Uhlig, F. Nov 2004 In : Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 59, 11-12, p. 1462-1470 9 p.

Research output: Contribution to journal › Article

Alkali Metals

Alkali metal compounds

Potassium

X ray crystallography

Hydrides

2003

17 Citations

An Examination of Metal-Ligand Binding Modes in Rubidium Diphenylmethanide

Alexander, J. S., Allis, D. G., Hudson, B. S. & Ruhlandt-Senge, K. Dec 10 2003 In : Journal of the American Chemical Society. 125, 49, p. 15002-15003 2 p.

Research output: Contribution to journal › Article

Rubidium

Crystallization

Metals

Ligands

Temperature

10 Citations

Electronic interactions in meso ferrocenyl porphyrin and its metal derivatives

Venkatraman, S., Prabhuraja, V., Mishra, R., Kumar, R., Chandrashekar, T. K., Teng, W. & Senge, K. R. Sep 2003 In : Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry. 42, 9, p. 2191-2197 7 p.

Research output: Contribution to journal › Article

Porphyrins

porphyrins

Metals

Derivatives

electronics

22 Citations

meso-substituted aromatic 34π core-modified octaphyrins: Syntheses, characterization and anion binding properties

Anand, V. G., Venkatraman, S., Rath, H., Chandrashekar, T. K., Teng, W. & Ruhlandt-Senge, K. May 23 2003 In : Chemistry - A European Journal. 9, 10, p. 2282-2290 9 p.

Research output: Contribution to journal › Article

Anions

Nuclear magnetic resonance

Thiophenes

Pyrroles

Molecular interactions

28 Citations

Syntheses and structures of barium silanides: Contact and separated ions

Teng, W., Englich, U. & Ruhlandt-Senge, K. Aug 11 2003 In : Angewandte Chemie (International Edition in English). 42, 31, p. 3661-3664 4 p.

Research output: Contribution to journal › Article

Barium

Alkaline Earth Metals

Organometallic Compounds

Ions

Alkaline earth metals

9 Citations

Syntheses and structures of magnesium pyridine thiolates - Model compounds for magnesium binding in photosystem I

Sousa Pedrares, A., Teng, W. & Ruhlandt-Senge, K. May 9 2003 In : Chemistry - A European Journal. 9, 9, p. 2019-2024 6 p.

Research output: Contribution to journal › Article

Magnesium Compounds

Photosystem I Protein Complex

Sulfur

Magnesium

Ligands